Stereoselective total synthesis of Oxylipin from open chain gluco-configured building block

摘要

Abstract Total synthesis of naturally occurring Oxylipin has been achieved from open chain gluco-configured building block which is readily assembled from inexpensive and commercially available D-(+)-gluconolactone. Grignard reaction and Wittig olefination reactions are key steps for the requisite CC bond formation. Graphical abstract Display Omitted Highlights ? Total synthesis of naturally occurring Oxylipin has been achieved from gluco-configured building block. ?