Homogeneous Water Oxidation by Half‐Sandwich Iridium(III) N‐Heterocyclic Carbene Complexes with Pendant Hydroxy and Amino Groups

Mahanti Bani; González?Miera Greco; Martínez‐Castro Elisa; Bedin Michele; Martín‐Matute Belén; Ott Sascha; Thapper Anders

摘要

Abstract > Herein, we report three Ir III Cp* complexes with hydroxy‐ or amino‐functionalized N‐heterocyclic carbene (NHC) ligands that catalyze efficient water oxidation induced by addition of ceric ammonium nitrate (CAN). The pendant hydroxy or amino groups are very important for activity, and the complexes with heteroatom‐functionalized NHC ligands show up to 15 times higher rates of oxygen evolution in CAN‐induced water oxidation than a reference Ir III Cp* complex without heteroatom functionalization. The formation of molecular high‐valent Ir intermediates that are presumably involved in the rate‐determining step for water oxidation is established by UV/Vis spectroscopy and ESI‐MS under turnover conditions. The hydroxy groups on the NHC ligands, as well as chloride ligands on the iridium center are proposed to structurally stabilize the high‐valent species, and thereby improve the catalytic activity. The Ir III complex with a hydroxy‐functionalized NHC shows the highest catalytic activity with a TON of 2500 obtained in 3?h and with 90?% yield relative to the amount of oxidant used. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 在此，我们报告了三个红外 iii </ sup> CP *羟基或氨基官能化的羟基官能化的N-杂环基石（NHC）配体，其催化通过添加硝酸铈铵（罐）诱导的有效水氧化。垂侧羟基或氨基对活性非常重要，并且具有杂原子官能化的NHC配体的络合物显示出比参考IR的水氧化在罐子诱导的水氧化中的速度较高的15倍。 iii </ sup> CP *没有杂原子官能化的复合物。可能是uV / Vis光谱和eSI-MS在流转条件下建立了可能参与水氧化速率测定步骤的分子高价红外中间体的形成。提出了NHC配体上的羟基，以及铱中心的氯化物配体，在结构上稳定了高价质的物种，从而改善了催化活性。他们的 iii </ sup> 与羟基官能化的NHC复合物显示出最高的催化活性，吨2500℃，其中3℃，相对于所用氧化剂的量为90倍。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16185/'>《ChemSusChem》</a> <b style="margin: 0 2px;">|</b><span>2017年第22期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mahanti Bani&option=202" target="_blank" rel="nofollow">Mahanti Bani;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=González?Miera Greco&option=202" target="_blank" rel="nofollow">González?Miera Greco;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Martínez‐Castro Elisa&option=202" target="_blank" rel="nofollow">Martínez‐Castro Elisa;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bedin Michele&option=202" target="_blank" rel="nofollow">Bedin Michele;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Martín‐Matute Belén&option=202" target="_blank" rel="nofollow">Martín‐Matute Belén;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ott Sascha&option=202" target="_blank" rel="nofollow">Ott Sascha;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thapper Anders&option=202" target="_blank" rel="nofollow">Thapper Anders;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryUppsala UniversityP.O. Box 523 75120 Uppsala Sweden;</p> <p>Department of Organic ChemistryArrhenius LaboratoryStockholm University 10691 Stockholm Sweden;</p> <p>Department of Organic ChemistryArrhenius LaboratoryStockholm University 10691 Stockholm Sweden;</p> <p>Department of ChemistryUppsala UniversityP.O. Box 523 75120 Uppsala Sweden;</p> <p>Department of Organic ChemistryArrhenius LaboratoryStockholm University 10691 Stockholm Sweden;</p> <p>Department of ChemistryUppsala UniversityP.O. Box 523 75120 Uppsala Sweden;</p> <p>Department of ChemistryUppsala UniversityP.O. Box 523 75120 Uppsala Sweden;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=homogeneous catalysis&option=203" rel="nofollow">homogeneous catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=iridium&option=203" rel="nofollow">iridium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=N-heterocyclic carbenes&option=203" rel="nofollow">N-heterocyclic carbenes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=water oxidation&option=203" rel="nofollow">water oxidation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=water splitting&option=203" rel="nofollow">water splitting;</a> </p> <div class="translation"> 机译：均匀催化;铱;N-杂环碳;水氧化;水分裂; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022094660.html">Homogeneous Water Oxidation by Half‐Sandwich Iridium(III) N‐Heterocyclic Carbene Complexes with Pendant Hydroxy and Amino Groups</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mahanti Bani&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mahanti Bani,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=González?Miera Greco&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">González?Miera Greco,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Martínez‐Castro Elisa&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Martínez‐Castro Elisa,</a> <a href="/journal-foreign-16185/" target="_blank" rel="nofollow" class="tuijian_authcolor">ChemSusChem .</a> <span>2017</span><span>,第22期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：半三明治铱（III）N-杂环卡宾配合物的均匀水氧化伴随羟基和氨基</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019760662.html">Novel and Versatile Imine-N-Heterocyclic Carbene Half-Sandwich Iridium(III) Complexes as Lysosome-Targeted Anticancer Agents</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Yuliang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yang Yuliang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guo Lihua&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guo Lihua,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tian Zhenzhen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tian Zhenzhen,</a> <a href="/journal-foreign-21948/" target="_blank" rel="nofollow" class="tuijian_authcolor">Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics .</a> <span>2018</span><span>,第17期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：新颖和多功能的亚胺-N-杂环卡贝半三明治铱（III）复合物作为溶酶体靶向抗癌剂</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025605949.html">Half-sandwich Iridium(III) N-heterocyclic carbene antitumor complexes and biological applications</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Yali&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Han Yali,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tian Zhenzhen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tian Zhenzhen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Shumiao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhang Shumiao,</a> <a href="/journal-foreign-34789/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Inorganic Biochemistry: An Interdisciplinary Journal .</a> <span>2018</span><span>,第期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：半三明治铱（III）N-杂环肉菜抗肿瘤复合物和生物应用</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-273145_thesis/0705015148468.html">CYCLOMETALATED IRIDIUM(III) AQUO COMPLEXES: EFFICIENT AND TUNABLE CATALYSTS FOR THE HOMOGENEOUS OXIDATION OF WATER</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Neal D. McDaniel&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Neal D. McDaniel,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Frederick J. Coughlin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Frederick J. Coughlin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Leonard L. Tinker&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Leonard L. Tinker </a> <a href="/conference-foreign-273145/" target="_blank" rel="nofollow" class="tuijian_authcolor">ACS National Meeting Exposition .</a> <span>2008</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：环状氧化铱（III）Aquo复合物：用于均匀氧化水的高效和可调催化剂</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061262261.html">Catalytic homogeneous hydrogenation of olefins using N-heterocyclic carbene complexes of rhodium and iridium.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Vazquez-Serrano, Leslie D.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Vazquez-Serrano, Leslie D. </a> <span>2004</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用铑和铱的N-杂环卡宾配合物催化烯烃的均相加氢。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040006192504.html">Imidazole and Benzimidazole Modified Half-Sandwich IridiumIIIN-Heterocyclic Carbene Complexes: Synthesis Anticancer Application and Organelle Targeting</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xicheng Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xicheng Liu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yali Han&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yali Han,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xingxing Ge&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xingxing Ge,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：咪唑和苯并咪唑改性的半三明治铱IIIIN-杂环碳烯配合物：合成抗癌应用和细胞器靶向。</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000127704112.html">Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yuki Suna&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yuki Suna,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mehmed Z. Ertem&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mehmed Z. Ertem,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wan-Hui Wang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wan-Hui Wang,</a> <span>2014</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：羟基对质子响应半三明治CP *铱（III）复合物催化活性的位置效应</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-suzhou-university-science-technology-natural-edition_thesis/0201250727279.html">新型N-杂环卡宾环金属铱配合物的合成</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周宇扬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 周宇扬</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谢凯&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,谢凯</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王筱梅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王筱梅</a> <span> <a href="/journal-cn-4718/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 苏州科技学院学报（自然科学版） </a> </span> <span> . 2016</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201292763558.html">邻-酚羟基取代N-杂环卡宾C，O螯合烯丙基钯配合物／MAO催化降冰片烯的聚合</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李立辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李立辉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=冯燕&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,冯燕</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李波&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李波</a> <span> <a href="/journal-cn-56862/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高分子材料科学与工程 </a> </span> <span> . 2008</span><span>,第10期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-guangdong-pharmaceutical-university_thesis/0201217902857.html">N-杂环卡宾钯配合物高效催化杂环类铃木偶联反应的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陆冬冬1&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陆冬冬1</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡立群1&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,胡立群1</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘丰收1&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘丰收1</a> <span> <a href="/journal-cn-21770/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广东药科大学学报 </a> </span> <span> . 2018</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-guangdong-college-pharmacy_thesis/0201243899611.html">N-杂环卡宾钯配合物高效催化杂环类铃木偶联反应的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陆冬冬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陆冬冬</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡立群&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,胡立群</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘丰收&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘丰收</a> <span> <a href="/journal-cn-6486/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广东药学院学报 </a> </span> <span> . 2018</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-hebei-university-technology_thesis/020129206121.html">利用银卡宾法制备N-杂环卡宾铑配合物及其反应性的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=彭学刚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 彭学刚</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=于晓燕&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,于晓燕</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张庆新&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张庆新</a> <span> <a href="/journal-cn-7520/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 河北工业大学学报 </a> </span> <span> . 2013</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-9177_thesis/020222301120.html">N-杂环卡宾金属配合物的制备及其应用</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=靳理坤&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 靳理坤</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈雨虹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈雨虹</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=万力&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,万力</a> <span> <a href="/conference-cn-9177/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 全国第十七届有机和精细化工中间体学术交流会 </a> <span> <span> . 2011</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315213615.html">半三明治铱(Ⅲ)氨杂环卡宾抗肿瘤配合物的合成及活性研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韩雅丽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 韩雅丽</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120112753391.html">含有N-杂环卡宾配体的铱(III)配合物、其合成及其在癌症治疗中的用途</a> <b>[P]</b> . <span> 中国专利： CN112805288A </span> <span> . 2021-05-14</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120105893269.html">用于碳－硫和碳－氧偶联反应的聚N－杂环卡宾过渡金属配合物和N－杂环卡宾过渡金属配合物</a> <b>[P]</b> . <span> 中国专利： CN101687723A </span> <span> . 2010-03-31</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130500829217.html">IRIDIUM (III) COMPLEXES CONTAINING N-HETEROCYCLIC CARBENE LIGAND, SYNTHESIS, AND THEIR USE THEREOF IN CANCER TREATMENT</a> <b>[P]</b> . <span> 外国专利：  US2021317153A1 </span> <span> . 2021-10-14</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铱（III）配合物含有N-杂环卡宾配体，合成及其在癌症治疗中的用途 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130401070425.html">IRIDIUM (III) COMPLEXES CONTAINING N-HETEROCYCLIC CARBENE LIGAND, SYNTHESIS, AND THEIR USE THEREOF IN CANCER TREATMENT</a> <b>[P]</b> . <span> 外国专利：  WO2020024969A1 </span> <span> . 2020-02-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含正杂碳配体的铱（III）配合物，合成及其在癌症治疗中的用途 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130401134349.html">NOVEL IONIC HALF SANDWICH RUTHENIUM COMPLEXES SUPPORTED BY N-HETEROCYCLIC CARBENE AND/OR PHOSPHINES, AS EFFICIENT TRANSFER HYDROGENATION CATALYSTS</a> <b>[P]</b> . <span> 外国专利：  CA3024425A1 </span> <span> . 2020-06-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：作为高效转移加氢催化剂的新型非离子半三明治式钌络合物，由N-杂环碳和/或膦支持 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022094660','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704022094660down" data-source="7," data-out-id="CZymfnYnADUZC7LKtDBZ6F1VkmPbCBkpb6PM2dIrNzmiQFsltNQHebO95gkQn67A," data-f-source-id="7" data-title="Homogeneous Water Oxidation by Half‐Sandwich Iridium(III) N‐Heterocyclic Carbene Complexes with Pendant Hydroxy and Amino Groups" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="0704022094660" id="docid"> <input type="hidden" value="16185" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Homogeneous Water Oxidation by Half‐Sandwich Iridium(III) N‐Heterocyclic Carbene Complexes with Pendant Hydroxy and Amino Groups"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/zq.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/common.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/top.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/tip.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/login.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/down.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/search.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/newmail.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/page.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/searchtype.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/user/regist.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/zxs_solor/reference.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/sse.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/util/cookie.js?v=5.8.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.8.7"></script> </body> <script> function kefu(customization) { var from = GetQueryString("from"); if (from == null || from == "") { from = "other"; } var url = getWxWorkQrCode(73, from, customization); if (url == "" || typeof url == 'undefined') { url = "https://wework.qpic.cn/wwpic/994838_0LUTS-VqR0quT1N_1675665967/0"; } tipDocGuidance(url, '人工辅助获取外文期刊材料'); } $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) function toCoverPage(){ var sourcetype=$("#sourcetype").val var fromStr=""; if(sourcetype==0){ fromStr="pc-wwoaxiangqing"; } if(sourcetype==4){ fromStr="pc-wwdetail-title"; } if(sourcetype==5){ fromStr="pc-wwhuiyixiangqing"; } window.location.href=url+"/zhichengpingshenlunwen.html?from="+fromStr; } </script> </html>