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首页> 外文期刊>Chemistry, an Asian journal >Highlights on the Road towards Highly Emitting Solid‐State Luminophores: Two Classes of Thiazole‐Based Organoboron Fluorophores with the AIEE/AIE Effect xmlns='http://www.wiley.com/namespaces/wiley' href='#asia201701526-note-1001'/>
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Highlights on the Road towards Highly Emitting Solid‐State Luminophores: Two Classes of Thiazole‐Based Organoboron Fluorophores with the AIEE/AIE Effect xmlns='http://www.wiley.com/namespaces/wiley' href='#asia201701526-note-1001'/>

机译：在高度发光的固态发光小团的道路上亮点：两类噻唑类有机硼荧光团，具有AIEE / AIE效应 xmlns =“http://www.wiley.com/namespaces/wiley”href =“＃asia201701526-noto-1001”/>

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Abstract > Developing a novel, small‐sized molecular building block that may be capable of emitting light in the solid state is a challenging task and has rarely been reported in the literature. BF <sub>2</sub> ‐containing dyes seem to be promising candidates towards this aim. Two series of new N^NBF <sub>2</sub> complexes showing aggregation‐induced emission (AIE) and aggregation‐induced emission enhancement (AIEE) were designed and synthesized by means of a new protocol, which improved on the traditional method by employing microwave irradiation. The optical and photophysical properties of the BF <sub>2</sub> complexes were investigated in depth. The synthesized complexes showed fluorescence in both solution and the solid state and, in a mixture of tetrahydrofuran/water, may aggregate into fluorescent nanoparticles. The experimental investigation was supported by quantum mechanical calculations. Their availability, stability, large Stokes shifts, and aggregation capabilities, along with their solid‐state emission capability, render this new class of BF <sub>2</sub> complexes promising AIEE/AIE fluorophores for further applications in the fields of fluorescence imaging and materials science. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <标题类型=“main”>抽象</ title> > 开发一种可以在固态发光的新颖的小型分子构建块是一个具有挑战性的任务，并且很少在文献中报道。 BF. <sub> 2 </ sub> - 染色似乎是对此目的的承诺候选人。两个系列新的n ^ nbf <sub> 2 </ sub> 通过新的协议设计和合成了显示聚集诱导的发射（AIE）和聚集诱导的发射增强（AIEE）的复合物，通过采用微波辐射来改善传统方法的新方案。 BF的光学和光物理性质 <sub> 2 </ sub> 深入研究了复合物。合成的配合物在溶液和固态中显示出荧光，并且在四氢呋喃/水的混合物中，可以聚集成荧光纳米颗粒。量子力学计算支持实验研究。它们的可用性，稳定性，大型斯托克斯班次和聚合能力以及它们的固态排放能力，呈现这类新的BF <sub> 2 </ sub> 复合物有前途的Aiee / AIE荧光团，用于荧光影像和材料科学领域的进一步应用。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16161/'>《Chemistry, an Asian journal》</a> <b style="margin: 0 2px;">|</b><span>2018年第3期</span><b style="margin: 0 2px;">|</b><span>共14页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lugovik Kseniya I.&option=202" target="_blank" rel="nofollow">Lugovik Kseniya I.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Eltyshev Alexander K.&option=202" target="_blank" rel="nofollow">Eltyshev Alexander K.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Suntsova Polina O.&option=202" target="_blank" rel="nofollow">Suntsova Polina O.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Slepukhin Pavel A.&option=202" target="_blank" rel="nofollow">Slepukhin Pavel A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Benassi Enrico&option=202" target="_blank" rel="nofollow">Benassi Enrico;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Belskaya Nataliya P.&option=202" target="_blank" rel="nofollow">Belskaya Nataliya P.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Ural Federal University19 Mira Str. Yekaterinburg 620002 Russian Federation;</p> <p>Ural Federal University19 Mira Str. Yekaterinburg 620002 Russian Federation;</p> <p>Ural Federal University19 Mira Str. Yekaterinburg 620002 Russian Federation;</p> <p>Ural Federal University19 Mira Str. Yekaterinburg 620002 Russian Federation;</p> <p>School of Science and TechnologyNazarbaev University53 Kabanbay Batyr Ave. Astana 010000 Republic of Kazakhstan;</p> <p>Ural Federal University19 Mira Str. Yekaterinburg 620002 Russian Federation;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=boron&option=203" rel="nofollow">boron;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=donor–acceptor systems&option=203" rel="nofollow">donor–acceptor systems;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electron transfer&option=203" rel="nofollow">electron transfer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fluorescence&option=203" rel="nofollow">fluorescence;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=thiazoles&option=203" rel="nofollow">thiazoles;</a> </p> <div class="translation"> 机译：硼;捐助者 - 受体系统;电子转移;荧光;噻唑; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022087433.html">Highlights on the Road towards Highly Emitting Solid‐State Luminophores: Two Classes of Thiazole‐Based Organoboron Fluorophores with the AIEE/AIE 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