Complexation Between ( <i xmlns='http://www.wiley.com/namespaces/wiley'>OO ‐Methyl) <sub xmlns='http://www.wiley.com/namespaces/wiley'>6</sub>6 ‐2,6‐Helic[6]arene and Tertiary Ammonium Salts: Acid/Base‐ or Chloride‐Ion‐Responsive Host–Guest Systems and Synthesis of [2]Rotaxane

Shi Qiang; Han Ying; Chen Chuan‐Feng

摘要

Abstract > Complexation between ( O ‐methyl) <sub>6</sub> ‐2,6‐helic[6]arene and a series of tertiary ammonium salts was described. It was found that the macrocycle could form stable complexes with the tested aromatic and aliphatic tertiary ammonium salts, which were evidenced by 1 H?NMR spectra, ESI mass spectra, and DFT calculations. In particular, the binding and release process of the guests in the complexes could be efficiently controlled by acid/base or chloride ions, which represents the first acid/base‐ and chloride‐ion‐responsive host–guest systems based on macrocyclic arenes and protonated tertiary ammonium salts. Moreover, the first 2,6‐helic[6]arene‐based [2]rotaxane was also synthesized from the condensation between the host–guest complex and isocyanate. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >之间的复杂化（ O </ i> - 甲基）<sub> 6 </ sub> -2,6-螺旋[6]芳烃和一系列叔铵盐。发现宏循环可以形成稳定的复合物，其用测试的芳族和脂族叔铵盐形成，其通过 1-sup> h 2 nMR光谱，ESI质谱和DFT计算来证明。特别地，复合物中的客人的结合和释放方法可以通过酸/碱或氯离子有效地控制，其代表基于宏环的第一酸/碱和氯离子响应寄主系统和质子叔铵盐。此外，第一2,6-螺旋[6]基于芳烃的[2]旋烷也从宿主 - 客户络合物和异氰酸酯之间的缩合合成。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16161/'>《Chemistry, an Asian journal》</a> <b style="margin: 0 2px;">|</b><span>2017年第19期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shi Qiang&option=202" target="_blank" rel="nofollow">Shi Qiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Ying&option=202" target="_blank" rel="nofollow">Han Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Chuan‐Feng&option=202" target="_blank" rel="nofollow">Chen Chuan‐Feng;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Beijing National Laboratory for Molecular SciencesChinese Academy of SciencesBeijing 100190 China;</p> <p>Beijing National Laboratory for Molecular SciencesChinese Academy of SciencesBeijing 100190 China;</p> <p>Beijing National Laboratory for Molecular SciencesChinese Academy of SciencesBeijing 100190 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ammonium&option=203" rel="nofollow">ammonium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=complexation&option=203" rel="nofollow">complexation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=host–guest systems&option=203" rel="nofollow">host–guest systems;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=macrocycles&option=203" rel="nofollow">macrocycles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rotaxanes&option=203" rel="nofollow">rotaxanes;</a> </p> <div class="translation"> 机译：铵;络合;寄宿机构系统;宏ycles;轮剑; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022087102.html">Front Cover: Complexation Between ( <i xmlns="http://www.wiley.com/namespaces/wiley">OO ‐Methyl) <sub xmlns="http://www.wiley.com/namespaces/wiley">6</sub>6 ‐2,6‐Helic[6]arene and Tertiary Ammonium Salts: Acid/Base‐ or Chloride‐Ion‐Responsive Host–Guest Systems and Synthesis of [2]Rotaxane (Chem. Asian J. 19/2017)</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shi Qiang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shi Qiang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Ying&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Han Ying,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Chuan‐Feng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen Chuan‐Feng </a> <a href="/journal-foreign-16161/" target="_blank" rel="nofollow" class="tuijian_authcolor">Chemistry, an Asian journal .</a> <span>2017</span><span>,第19期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：前封面：（<i xmlns =“http://www.wiley.com/namespaces/wiley”> O </ i> o -methyl）<sub xmlns =“http://www.wiley.com/ 名称空间/瓦西“> 6 </ sub> 6 -2,6-Helic [6]芳烃和叔铵盐：酸/碱或氯离子响应宿主访客系统和合成[2]甲烷（Chem。亚洲J. 19/2017）</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019838958.html">[( <i xmlns="http://www.wiley.com/namespaces/wiley">parapara ‐Cymene)Ru(dppp)Cl][PF <sub xmlns="http://www.wiley.com/namespaces/wiley">6</sub>6 ]‐Catalysed Stereospecific Synthesis of <i xmlns="http://www.wiley.com/namespaces/wiley">OO ‐Dienyl Esters, and Evaluation of the Anticancer Activity of a Long‐Chain Fatty Acid <i xmlns="http://www.wiley.com/namespaces/wiley">OO ‐Dienyl Ester</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jena Rajesh K.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jena Rajesh K.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rajesh Y.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Rajesh Y.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mandal Mahitosh&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mandal Mahitosh,</a> <a href="/journal-foreign-23259/" target="_blank" rel="nofollow" class="tuijian_authcolor">European journal of organic chemistry .</a> <span>2017</span><span>,第11期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：[（<i xmlns =“http://www.wiley.com/namespaces/wiley”> para </ i> para -cymene）ru（dppp）cl] [pf <sub xmlns ='http：// www。 wiley.com/namespaces/wiley"1mp</sub -sub -6] -catysed的立体特异性合成<i xmlns =“http://www.wiley.com/namespaces/wiley”> O </ i> o -dienyl酯，并评估长链脂肪酸的抗癌活性<i xmlns =“http://www.wiley.com/namespaces/wiley”> O </ i> o -dienyl酯</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020726418.html">Initiator‐free atom transfer radical polymerization of methyl methacrylate based on FeBr <sub xmlns="http://www.wiley.com/namespaces/wiley">3</sub>3 (PPh <sub xmlns="http://www.wiley.com/namespaces/wiley">3</sub>3 ) <sub xmlns="http://www.wiley.com/namespaces/wiley"> n </sub> <i xmlns="http://www.wiley.com/namespaces/wiley">nn system</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Danfeng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yang Danfeng,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Jirong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Jirong,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Jianyu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Han Jianyu,</a> <a href="/journal-foreign-35621/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Polymer Science, Part A. Polymer Chemistry .</a> <span>2017</span><span>,第23期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于FEBR <SUB XMLNS =“http://www.wiley.com/namespaces/wiley”> 3 </ sub> 3（pph <sub xmlns =“http：// www.wiley.com/namespaces/wiley">3,1/sub>3）<sub xmlns =“http://www.wiley.com/namespaces/wiley”> n </ i> </ sub> <i xmlns =“http://www.wiley.com/namespaces/wiley”> n </ i> n系统</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040001773414.html">Catalytic Asymmetric Synthesis 2nd Edition. By Iwao Ojima (Editor)Wiley-VCH: New York (http://www.wiley.com/). 2000. Pages: XIV 864 Pages Hardcover. Price: 169.- Euro / 330.54 DM / 294.- SFR. ISBN: 0-471-29805-0</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <span>2001</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：催化不对称合成第二版。奥利马（Iwao Ojima）（编辑）Wiley-VCH：纽约（http://www.wiley.com/）。 2000。页数：XIV864页精装。价格：169.-欧元/330.54 DM / 294.- SFR。国际标准书号（ISBN）：0-471-29805-0</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000126405104.html">Front Cover: Complexation Between (O -Methyl)6 -2,6-Helic6arene and Tertiary Ammonium Salts: Acid/Base- or Chloride-Ion-Responsive Host-Guest Systems and Synthesis of 2Rotaxane (Chem. Asian J. 19/2017)</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qiang Shi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Qiang Shi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ying Han&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ying Han,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chuan-Feng Chen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chuan-Feng Chen </a> <span>2017</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：前盖：（O-甲基）6 -2,6-Helic 6芳烃和叔铵盐之间的络合：酸/碱或氯离子响应宿主 - 访客系统和合成2甲烷（化学。亚洲J. 19/2017）</span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022087115','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704022087115down" data-source="7," data-out-id="Hck+kgMBadYvQhY6ZNFMvg==," data-f-source-id="7" data-title="Complexation Between ( <i xmlns='http://www.wiley.com/namespaces/wiley'>OO ‐Methyl) <sub xmlns='http://www.wiley.com/namespaces/wiley'>6</sub>6 ‐2,6‐Helic[6]arene and Tertiary Ammonium Salts: Acid/Base‐ or Chloride‐Ion‐Responsive Host–Guest Systems and Synthesis of [2]Rotaxane" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="16161" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Complexation Between ( <i xmlns='http://www.wiley.com/namespaces/wiley'>OO ‐Methyl) <sub xmlns='http://www.wiley.com/namespaces/wiley'>6</sub>6 ‐2,6‐Helic[6]arene and Tertiary Ammonium Salts: Acid/Base‐ or Chloride‐Ion‐Responsive Host–Guest Systems and Synthesis of [2]Rotaxane"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>

Complexation Between ( OO ‐Methyl) 66 ‐2,6‐Helic[6]arene and Tertiary Ammonium Salts: Acid/Base‐ or Chloride‐Ion‐Responsive Host–Guest Systems and Synthesis of [2]Rotaxane

摘要

Complexation Between ( OO ‐Methyl) ₆6 ‐2,6‐Helic[6]arene and Tertiary Ammonium Salts: Acid/Base‐ or Chloride‐Ion‐Responsive Host–Guest Systems and Synthesis of [2]Rotaxane