Co‐generation of Ammonia and H2 from H2O Vapor and N2 Using a Membrane Electrode Assembly

Kugler Kurt; Kriescher Stefanie M. A.; Giela Martin; Hosseiny Schwan; Thimm Kristof; Wessling Matthias

摘要

Abstract > The direct electrochemical synthesis of NH <sub>3</sub> from nitrogen and water vapor without the use of a fossil carbon source is highly desired. This synthesis is a viable option to store energy and produce fertilizer precursors. Here, a new Pt‐free membrane electrode assembly is presented. An electrochemical membrane reactor demonstrates the feasibility of co‐generating NH <sub>3</sub> and H <sub>2</sub> directly from nitrogen and water vapor at ambient conditions. An unprecedented high NH <sub>3</sub> ‐specific current efficiency of up to 27.5% using Ti as cathodic catalyst is reported. The co‐generation can be tuned by the balance of process parameters. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > NH的直接电化学合成 <sub> 3 </ sub> 从氮气和水蒸气不需要使用而不使用化石碳源。该合成是存放能量和生产肥料前体的可行选择。这里，提出了一种新的PT免膜电极组件。电化学膜反应器证明了共同产生NH的可行性 <sub> 3 </ sub> 和H. <sub> 2 </ sub> 直接来自环境条件下的氮气和水蒸气。一个前所未有的高NH <sub> 3 </ sub> 报告了使用Ti作为阴极催化剂的特异性高达27.5％的电流效率。可以通过工艺参数的余额来调整同源。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16114/'>《Chemie-Ingenieur-Technik: Verfahrenstechnik Technische Chemie Apparatewesen Biotechnologie 》</a> <b style="margin: 0 2px;">|</b><span>2020年第2期</span><b style="margin: 0 2px;">|</b> <span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kugler Kurt&option=202" target="_blank" rel="nofollow">Kugler Kurt;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kriescher Stefanie M. A.&option=202" target="_blank" rel="nofollow">Kriescher Stefanie M. A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Giela Martin&option=202" target="_blank" rel="nofollow">Giela Martin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hosseiny Schwan&option=202" target="_blank" rel="nofollow">Hosseiny Schwan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thimm Kristof&option=202" target="_blank" rel="nofollow">Thimm Kristof;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wessling Matthias&option=202" target="_blank" rel="nofollow">Wessling Matthias;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Chemical Process EngineeringRWTH Aachen UniversityForckenbeckstra?e 51 52074 Aachen Germany;</p> <p>Chemical Process EngineeringRWTH Aachen UniversityForckenbeckstra?e 51 52074 Aachen Germany;</p> <p>Chemical Process EngineeringRWTH Aachen UniversityForckenbeckstra?e 51 52074 Aachen Germany;</p> <p>Chemical Process EngineeringRWTH Aachen UniversityForckenbeckstra?e 51 52074 Aachen Germany;</p> <p>Chemical Process EngineeringRWTH Aachen UniversityForckenbeckstra?e 51 52074 Aachen Germany;</p> <p>Chemical Process EngineeringRWTH Aachen UniversityForckenbeckstra?e 51 52074 Aachen Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/238.html" title="化学工业">化学工业 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ammonia&option=203" rel="nofollow">Ammonia;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Electrochemical nitrogen reduction&option=203" rel="nofollow">Electrochemical nitrogen reduction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Haber process&option=203" rel="nofollow">Haber process;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Membrane electrode assembly&option=203" rel="nofollow">Membrane electrode assembly;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Renewable energy&option=203" rel="nofollow">Renewable energy;</a> </p> <div class="translation"> 机译：氨;电化学氮气减少;Haber工艺;膜电极组件;可再生能源; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022073242.html">Co‐generation of Ammonia and H2 from H2O Vapor and N2 Using a Membrane Electrode Assembly</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kugler Kurt&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kugler Kurt,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kriescher Stefanie M. 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href="/patent-detail/06120106278054.html">用于膜电极组件的活化方法、膜电极组件以及使用膜电极组件的固体聚合物型燃料电池</a> <b>[P]</b> . <span> 中国专利： CN102077400A </span> <span> . 2011-05-25</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120106286512.html">质子传导性复合电解质、使用其的膜电极组件、以及使用膜电极组件的电化学装置</a> <b>[P]</b> . <span> 中国专利： CN102105945A </span> <span> . 2011-06-22</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130499732951.html">A gas injection device capable of suppressing the generation of wrinkles of a electrolyte membrane, membrane-electrode assembly manufacturing apparatus comprising the same and A method for manufacturing membrane-electrode assembly</a> <b>[P]</b> . <span> 外国专利：  KR20210035542A </span> <span> . 2021-04-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：一种气体注射装置，其能够抑制电解质膜的皱纹，包括相同的膜 - 电极组件制造装置和制造膜 - 电极组件的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130403348728.html">- Method for electrochemical ammonia synthesis using anion-exchange membrane-type membrane electrode assembly</a> <b>[P]</b> . <span> 外国专利：  KR101924490B1 </span> <span> . 2018-12-04</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-使用阴离子交换膜型膜电极组件的电化学合成氨的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130441254784.html">Flat fuel cell with an electrode-membrane-electrode assembly using a tissue membrane divided into conducting and insulating zones, for the generation of electric power for stationary, transport or portable applications</a> <b>[P]</b> . <span> 外国专利：  FR2852736A1 </span> <span> . 2004-09-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：带有电极-膜-电极组件的扁平燃料电池，其组织膜分为导电区和绝缘区，用于固定，运输或便携式应用中的发电 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022073242','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p 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