Tungsten‐Nitride‐Coated Carbon Nanospheres as a Sulfur Host for High‐Performance Lithium‐Sulfur Batteries

Liu Honghong; Shen Hangjia; Li Rongrong; Liu Siqi; Turak Ayse; Yang Minghui

摘要

Abstract > Lithium‐sulfur batteries have attracted wide attention, owing to their outstanding properties such as high theoretical specific capacity, low cost, and non‐toxic nature. However, the low conductivity of the sulfur cathode and its shuttling effects are still a challenge for the energy‐storage system. In this work, we describe a potential solution to address this challenge, using carbon nanospheres encapsulated in a tungsten nitride (WN) layer, interconnected with WN nanorods. After successfully synthesizing this composite in?situ by using a straightforward method, we applied it as the sulfur host for lithium‐sulfur batteries. The results demonstrate a strong chemical trapping ability of the WN shell towards lithium polysulfides (LiPSs), and a strong electron‐transfer ability of the WN nanorods. Together, these effects alleviate LiPSs′ shuttling from carbon nanospheres (CNS) and give rise to a high sulfur content (70?wt?%) in the as‐prepared S/WN‐CNS material. When compared to traditional S/N‐CNS electrodes, the tuned S/WN‐CNS cathodes deliver an outstanding electrochemical performance, including a high initial capacity of 1351?mAh?g ?1 at 0.1?C and superior long‐term cycling stability with 80?% retention of the initial capacity with 3?mg?cm ?2 after 500?cycles at 0.5?C. As such, a high specific capacity, excellent rate capacity, and long cycling stability are achieved. Our approach provides a path to a broad class of high‐performance Li‐S battery applications based on nanostructured WN materials. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 锂 - 硫磺电池引起了广泛的关注，由于其优异的性质，如高理论特异性容量，低成本和无毒性。然而，硫阴极的低导电性及其穿梭效果仍然是能量储存系统的挑战。在这项工作中，我们描述了使用包封在氮化物（WN）层中的碳纳米球来解决这一挑战的潜在解决方案，与WN纳米棒相互连接。通过使用简单的方法成功地合成该复合材料，我们将其施加为锂 - 硫电池的硫磺宿主。结果表明，WN壳对多硫化物（嘴唇）的强化学捕获能力，以及WN纳米棒的强电子传递能力。这些效果在一起减轻了从碳纳米球（CNS）的唇嘴，并在制备的S / WN-CNS材料中产生高硫含量（70·wt≤％）。与传统的S / N-CNS电极相比，调谐的S / WN-CNS阴极提供出色的电化学性能，包括高初始容量为1351？MAH？G. ？1 </ sup> 在0.1？c和优异的长期循环稳定性，80〜％的初始容量保持3？mg？cm ？2 </ sup> 500℃之后？循环0.5？c。因此，实现了高特定容量，优异的速率和长循环稳定性。我们的方法提供了一种基于纳米结构WN材料的广泛高性能Li-S电池应用的路径。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16042/'>《ChemElectroChem》</a> <b style="margin: 0 2px;">|</b><span>2019年第7期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Honghong&option=202" target="_blank" rel="nofollow">Liu Honghong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shen Hangjia&option=202" target="_blank" rel="nofollow">Shen Hangjia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Rongrong&option=202" target="_blank" rel="nofollow">Li Rongrong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Siqi&option=202" target="_blank" rel="nofollow">Liu Siqi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Turak Ayse&option=202" target="_blank" rel="nofollow">Turak Ayse;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Minghui&option=202" target="_blank" rel="nofollow">Yang Minghui;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Solid State functional Materials Research Laboratory Institution Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201 China;</p> <p>Solid State functional Materials Research Laboratory Institution Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201 China;</p> <p>Solid State functional Materials Research Laboratory Institution Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201 China;</p> <p>Solid State functional Materials Research Laboratory Institution Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201 China;</p> <p>Department of Engineering PhysicsMcMaster UniversityHamilton L8 S4 L7 Canada;</p> <p>Solid State functional Materials Research Laboratory Institution Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium-sulfur batteries&option=203" rel="nofollow">lithium-sulfur batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cathode materials&option=203" rel="nofollow">cathode materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tungsten nitride&option=203" rel="nofollow">tungsten nitride;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=chemical adsorption&option=203" rel="nofollow">chemical adsorption;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=shuttling effects&option=203" rel="nofollow">shuttling effects;</a> </p> <div class="translation"> 机译：锂 - 硫磺电池;阴极材料;钨氮化物;化学吸附;穿梭效果; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_transactions-nonferrous-metals-society-china_thesis/0201270902038.html">高性能可充式锂硒电池多孔分散碳球/硒复合物的合成与表征</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=颜军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">颜军,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘维芳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">刘维芳,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈诚&option=202" target="_blank" rel="nofollow" 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硫磺电池：紧凑型氮掺杂碳纳米片/钼磷纳米晶体中空纳米球作为高性能锂硫化学的多硫化物储层（小40/2019）</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_plastics-additives_thesis/0201248282206.html">硫磺熏蒸PO涂覆棚膜的防老化技术进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周大纲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 周大纲</a> <span> <a href="/journal-cn-9213/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 塑料助剂 </a> </span> <span> . 2017</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_spectroscopy-spectral-analysis_thesis/0201232974302.html">钨盐涂覆-GFAAS法测定肿瘤患者体内痕量锂</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周健&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 周健</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孙昕&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,孙昕</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=窦红漫&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,窦红漫</a> <span> <a href="/journal-cn-11127/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 光谱学与光谱分析 </a> </span> <span> . 1999</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-power-sources_thesis/0201230303279.html">斯坦福大学用中空碳纳米球制备出纯锂阳极</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘兰兰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘兰兰</a> <span> <a href="/journal-cn-8483/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 电源技术 </a> </span> <span> . 2014</span><span>,第009期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-66516_thesis/020222984959.html">电纺丝法制备分级Co3O4/中空碳纳米球@碳纳米纤维锂硫电池的正极材料</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=HE Lei&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . HE Lei</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=贺磊&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,贺磊</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=LIU Rui-feng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,LIU Rui-feng</a> <span> <a href="/conference-cn-66516/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十三届全国新型炭材料学术研讨会 </a> <span> <span> . 2017</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315244972.html">碳及其复合材料在高性能锂基和钠基电池中的应用研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=汪涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 汪涛</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120105235949.html">含有硫磺和/或具有S－S键的硫磺化合物的电池正极材料及其制造方法</a> <b>[P]</b> . <span> 中国专利： CN101027803A </span> <span> . 2007-08-29</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120103723615.html">用于制备颗粒状碳涂覆的磷酸铁锂的方法、碳涂覆的磷酸铁锂及其用途</a> <b>[P]</b> . <span> 中国专利： CN111094177A </span> <span> . 2020-05-01</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130407586408.html">Thin-film sulfur-coated activated carbon manufacturing method, thin-film sulfur-coated activated carbon, positive electrode mixture and all-solid-state lithium-sulfur battery</a> <b>[P]</b> . <span> 外国专利：  JP6278301B2 </span> <span> . 2018-02-14</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：薄膜硫包覆活性炭的制造方法，薄膜硫包覆活性炭，正极合剂及全固态锂硫电池 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130410486255.html">Method for producing thin-film sulfur-coated conductive carbon, thin-film sulfur-coated conductive carbon, positive electrode mixture, and all-solid-state lithium-sulfur battery</a> <b>[P]</b> . <span> 外国专利：  JP6160951B2 </span> <span> . 2017-07-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：薄膜硫包覆导电碳的制造方法，薄膜硫包覆导电碳，正极合剂及全固态锂硫电池 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130416135518.html">METHOD OF PRODUCING THIN FILM SULFUR-COATED ACTIVATED CARBON, THIN FILM SULFUR-COATED ACTIVATED CARBON, POSITIVE ELECTRODE MIXTURE, AND ALL-SOLID-STATE LITHIUM SULFUR BATTERY</a> <b>[P]</b> . <span> 外国专利：  JP2015088232A </span> <span> . 2015-05-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: 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