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Effects of Electrolytes on the Photocurrent of N‐Annulated Perylene‐Sensitized Photoelectrochemical Cells Based on NiO as Photocathode

机译:电解质对基于NIO作为光电阴极的NiO的N-环状前敏化光电子化细胞光电流的影响

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Abstract > The new organic dye NPP with N‐annulated perylene (NP) as donor, bithiophene as π bridge and perylenemonoimide (PMI) as acceptor has been synthesized and applied for dye‐sensitized photoelectrochemical cells (DSPEC). Phosphate (PBS), sodium sulfate (Na <sub>2</sub> SO <sub>4</sub> ) and acetate buffer solution (ABS) have been employed as electrolytes to investigate their effects on the photocurrent of the DSPEC. After 200?s illumination, PBS, ABS and Na <sub>2</sub> SO <sub>4</sub> based cells exhibited a photocurrent of ?13, ?7 and ?7?μA?cm ?2 , respectively. Electrochemical impedance spectroscopy (EIS) indicated that the DSPEC device with PBS as electrolyte showed the smallest charge transfer resistance (R <sub>ct</sub> ) and largest hole lifetime, which might best explain the highest photocurrent found for the PBS based device. In addition, incident monochromatic photon‐to‐electron conversion efficiency (IPCE) of the photoelectrochemical cells with PBS, ABS and Na <sub>2</sub> SO <sub>4</sub> aqueous solution as electrolytes was determined. The IPCE of the PBS based device was the highest at 430~620?nm and the result was consistent with the measured photocurrent. However, under long‐time illumination, the acetate buffer solution based device displayed the highest stability. Hence, the results show that the electrolytes have a significant effect on the photocurrent and stability of DSPECs. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml:lang =“en”> <标题类型=“main”>抽象</ title> > 已经合成了作为供体的N-链环(NP)的新有机染料NPP作为供体,白甲蛋白作为π桥和PMI),并施加用于染料敏化的光电化学电池(DSPEC)。磷酸盐(PBS),硫酸钠(NA <sub> 2 </ sub> 所以 <sub> 4 </ sub> )和乙酸盐缓冲溶液(ABS)已用作电解质,以研究它们对DSPEC的光电流的影响。 200次照明后,PBS,ABS和NA <sub> 2 </ sub> 所以 <sub> 4 </ sub> 基基细胞表现出α13,α7和α7Ω·厘米的光电流 ?2 </ sup> , 分别。电化学阻抗光谱(EIS)表明,具有PBS作为电解质的DSPEC器件显示最小的电荷转移电阻(R. <sub> ct </ sub> )最大的孔寿命,这可能最好解释基于PBS的设备的最高光电流。此外,与PBS,ABS和NA的光电化学电池的入射单色光子 - 电子转换效率(IPCE) <sub> 2 </ sub> 所以 <sub> 4 </ sub> 确定电解质水溶液。基于PBS的装置的IPCE在430〜620℃下最高,结果与测量的光电流一致。然而,在长时间照明下,基于醋酸盐的缓冲溶液的装置显示出最高的稳定性。因此,结果表明,电解质对DSPecs的光电流和稳定性具有显着影响。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16042/'>《ChemElectroChem 》</a> <b style="margin: 0 2px;">|</b><span>2018年第21期</span><b style="margin: 0 2px;">|</b> <span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Shicong&option=202" target="_blank" rel="nofollow">Zhang Shicong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Xing&option=202" target="_blank" rel="nofollow">Li Xing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yun Kang&option=202" target="_blank" rel="nofollow">Yun Kang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Fengtao&option=202" target="_blank" rel="nofollow">Yu Fengtao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hua Jianli&option=202" target="_blank" rel="nofollow">Hua Jianli;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Key Laboratory for Advanced Materials School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyNo. 130 Meilong Road Shanghai 200237 China;</p> <p>Key Laboratory for Advanced Materials School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyNo. 130 Meilong Road Shanghai 200237 China;</p> <p>Key Laboratory for Advanced Materials School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyNo. 130 Meilong Road Shanghai 200237 China;</p> <p>Key Laboratory for Advanced Materials School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyNo. 130 Meilong Road Shanghai 200237 China;</p> <p>Key Laboratory for Advanced Materials School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyNo. 130 Meilong Road Shanghai 200237 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学(理论化学)、化学物理学">物理化学(理论化学)、化学物理学 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=dye-sensitized photoelectrochemical cell&option=203" rel="nofollow">dye-sensitized photoelectrochemical cell;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrolyte&option=203" rel="nofollow">electrolyte;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=NiO&option=203" rel="nofollow">NiO;</a> </p> <div class="translation"> 机译:染料敏化的光电化学电池;电解质;nio; 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