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Bifunctional Catalysts Based on Tungsten Hydrides Supported on Silicated Alumina for the Direct Production of 2,3‐Dimethylbutenes and Neohexene from Isobutene

机译:基于硅化铝基氢化物的双官能催化剂用于直接产生2,3-二甲基丁烯和异丁烯的新甲烯

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Abstract >Well‐defined bifunctional supported catalysts that comprise tungsten hydride moieties and Br?nsted acid sites were prepared successfully. The catalysts showed outstanding activities and selectivities toward the formation of high‐value‐added products, 2,3‐dimethylbutenes and 3,3‐dimethylbutene, through a combination of the metathesis and dimerization of isobutene. The relationship between the physicochemical properties of the catalysts and their activities and selectivities indicated that isobutene conversion increased from 4 to 95?% as a function of the silica content of the silicated alumina (obtained from Sasol). Nevertheless, the selectivity toward branched hexenes showed a volcano‐shaped curve that presented a maximum for the catalyst with 5?wt?% silica. Therefore, the control of the support acidity by the silica loading on alumina resulted in an increase of the selectivity toward neohexene. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> >成功制备包含氢化钨部分和Brα的氢化物部分和Brαnsted酸部位的明确定义的双官能负载催化剂。通过组合异丁烯的复分解和二聚化,催化剂朝向形成高附加值的产物,2,3-二甲基丁烯和3,3-二甲基丁烯的优异活动和选择性。催化剂的物理化学性质与其活性和选择性之间的关系表明异丁烯转化率从4至95μm增加到硅藻的二氧化硅含量(从Sasol获得)的函数。然而,对支链己烯的选择性显示出催化剂的最大火山形曲线,其具有5·wt≤%二氧化硅。因此,对氧化铝的二氧化硅负载控制支持酸度导致对新甲烯的选择性增加。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16041/'>《ChemCatChem 》</a> <b style="margin: 0 2px;">|</b><span>2017年第12期</span><b style="margin: 0 2px;">|</b> <span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学(理论化学)、化学物理学">物理化学(理论化学)、化学物理学 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=dimerization&option=203" rel="nofollow">dimerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrides&option=203" rel="nofollow">hydrides;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metathesis&option=203" rel="nofollow">metathesis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tungsten&option=203" rel="nofollow">tungsten;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=supported catalysts&option=203" rel="nofollow">supported catalysts;</a> </p> <div class="translation"> 机译:二聚化;氢化物;复分解;钨;支持的催化剂; 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