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Immobilization of Pyrene‐Adorned N‐Heterocyclic Carbene Complexes of Rhodium(I) on Reduced Graphene Oxide and Study of their Catalytic Activity

机译：铑（I）的芘装饰的芘的N-杂环络合物的固定氧化石墨烯氧化物及其催化活性研究

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Abstract > Two pyrene‐tagged N‐heterocyclic carbene (NHC) complexes of rhodium(I) were obtained and characterized. The two complexes were supported onto reduced graphene oxide (rGO), generating two new materials in which the molecular complexes are immobilized by π–π stacking interactions onto the surface of the solid. The catalytic activity of both complexes and solid hybrid materials were studied in the 1,4‐addition of phenylboronic acid to cyclohex‐2‐one, and in the hydrosilylation of terminal alkynes. The studies showed that for both reactions, the dimetallic complex displayed better catalytic performances than the monometallic one. This accounted for both the reactions performed in homogeneous conditions and for the reactions performed with the solid. In the case of the addition of phenylboronic acid to cyclohexanone, the solid containing the dimetallic catalyst could be effectively recycled up to five times, with negligible loss of activity, whereas the monometallic catalyst rapidly became inactive. In the hydrosilylation of terminal alkynes, the selectivity towards the β‐( Z )vinylsilane was improved if the immobilized dimetallic catalyst was used, although the catalyst started to lose activity after the second run. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 获得两种芘标记的铑（I）的芘（I）络合物。将两种配合物负载在氧化物还原氧化物（RGO）上，产生两种新材料，其中将分子复合物通过π-π堆叠相互作用固定到固体表面上。在1,4-加入苯基硼酸至环己-2-1中，研究了复合物和固体杂化材料的催化活性，并在炔醇末端的氢化物中。这些研究表明，对于两种反应，二均金属复合物显示比单金属的催化性能更好。这占均匀条件下的反应和用固体进行的反应。在将苯基硼酸加入环己酮的情况下，含有二丙基催化剂的固体可以有效地再循环至五次，活性损失可忽略不计，而单金属催化剂迅速变为无活性。在炔醇末端的液体化，对β-的选择性（ z </ i> ）如果使用固定化的二金属催化剂，则改善乙烯基硅烷，但催化剂在第二次运行后开始失去活性。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16041/'>《ChemCatChem》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=catalyst immobilization&option=203" rel="nofollow">catalyst immobilization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=catalyst recyclability&option=203" rel="nofollow">catalyst recyclability;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphene&option=203" rel="nofollow">graphene;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=N-heterocyclic carbene&option=203" rel="nofollow">N-heterocyclic carbene;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rhodium&option=203" rel="nofollow">rhodium;</a> </p> <div class="translation"> 机译：催化剂固定化;催化剂再循环性;石墨烯;正杂环碳;铑; 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