Synergistic Production of Methyl Lactate from Carbohydrates Using an Ionic Liquid Functionalized Sn‐Containing Catalyst

Wang Fenfen; Wen Yi; Fang Yanxiong; Ji Hongbing

摘要

Abstract >Considerable progress has been made recently in the catalytic conversion of renewable biomass resources to methyl lactate (MLA). However, conceiving eco‐friendly and effective catalytic systems for the production of MLA from biomass carbohydrates remains a key challenge. Herein, we report a multifunctional catalyst Sn(salen)/IL, consisting of a Sn(salen) complex and an imidazolium‐based ionic liquid (IL), which acts via an intramolecular synergistic effect to convert carbohydrates to MLA in methanol. The versatile properties of the resultant catalyst were revealed to be responsible for the conversion of fructose to MLA and the efficient suppression of undesired side reactions. This catalyst displayed outstanding catalytic activity, high selectivity, and excellent recyclability, giving an MLA yield of up to 68.9?% at 160?°C after 2?h. The results of this study will contribute to new approaches for designing synergistic catalysts for producing liquid fuels and chemicals from biomass resources. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 最近在可再生生物质资源的催化转化为甲基甲酸甲酯（MLA）中进行了相当大的进展。然而，从生物质碳水化合物生产MLA的生态友好型催化系统仍然是一个关键挑战。在此，我们报告多官能催化剂Sn（Salen）/ IL，由Sn（Salen）复合物和基于咪唑鎓基离子液体（IL）组成，其通过分子内协同效应作用，以将碳水化合物转化为甲醇中的MLA。显示所得催化剂的多功能性质，以负责将果糖转化为MLA，并且有效地抑制不需要的副反应。该催化剂显示出优异的催化活性，高选择性和优异的再循环性，在2℃后，在160℃下的MLA产率高达68.9〜％。该研究的结果将有助于设计用于制备生物质资源的液体燃料和化学品的协同催化剂的新方法。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16041/'>《ChemCatChem》</a> <b style="margin: 0 2px;">|</b><span>2018年第18期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Fenfen&option=202" target="_blank" rel="nofollow">Wang Fenfen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wen Yi&option=202" target="_blank" rel="nofollow">Wen Yi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fang Yanxiong&option=202" target="_blank" rel="nofollow">Fang Yanxiong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ji Hongbing&option=202" target="_blank" rel="nofollow">Ji Hongbing;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Chemical Engineering and Light IndustryGuangdong University of TechnologyGuangzhou 510006 P.R. China;</p> <p>School of Chemical Engineering and Light IndustryGuangdong University of TechnologyGuangzhou 510006 P.R. China;</p> <p>School of Chemical Engineering and Light IndustryGuangdong University of TechnologyGuangzhou 510006 P.R. China;</p> <p>Fine Chemical Industry Research Institute School of ChemistrySun Yat-sen UniversityGuangzhou 510275 P.R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbohydrates&option=203" rel="nofollow">carbohydrates;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fructose&option=203" rel="nofollow">fructose;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=methyl lactate&option=203" rel="nofollow">methyl lactate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=synergistic catalysis&option=203" rel="nofollow">synergistic catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tin ion&option=203" rel="nofollow">tin ion;</a> </p> <div class="translation"> 机译：碳水化合物;果糖;乳酸甲酯;协同催化;锡离子; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022057068.html">Synergistic Production of Methyl Lactate from Carbohydrates Using an Ionic Liquid Functionalized Sn‐Containing Catalyst</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Fenfen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Fenfen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wen Yi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wen Yi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fang Yanxiong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Fang Yanxiong,</a> <a href="/journal-foreign-16041/" target="_blank" rel="nofollow" class="tuijian_authcolor">ChemCatChem .</a> <span>2018</span><span>,第18期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用离子液体官能化的含碳水化合物的碳水化合物乳酸甲酯的协同产生</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070402345566.html">Metal-Containing Ionic Liquids as Synergistic Catalysts for the Cycloaddition of CO2: A Density Functional Theory and Response Surface Methodology Corroborated Study</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dongwoo Kim&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dongwoo Kim,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yeji Moon&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yeji Moon,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dahye Ji&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dahye Ji </a> <a href="/journal-foreign-18131/" target="_blank" rel="nofollow" class="tuijian_authcolor">ACS Sustainable Chemistry & Engineering .</a> <span>2016</span><span>,第9期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含金属离子液体作为CO2环加成的协同催化剂：密度泛函理论和响应面方法学的确证研究</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025422040.html">Methyl lactate production from levoglucosan by using Sn-Beta and H-Beta catalysts</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luo Dan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Luo Dan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Shengnan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liu Shengnan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yin Wang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yin Wang,</a> <a href="/journal-foreign-33908/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Chemical Technology & Biotechnology .</a> <span>2020</span><span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过使用Sn-β和H-Beta催化剂从左葡聚糖乳酸乳酸盐产生</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-267230_thesis/0705012067873.html">IONIC LIQUIDS AS CATALYSTS FOR SULFURIC ACID PRODUCTION AND CLEANING OF FLUE GASES</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=RASMUS FEHRMANN&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">RASMUS FEHRMANN,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=K.M. 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href="/academic-conference-cn_meeting-27088_thesis/020221756422.html">一株乳杆菌的分离鉴定与碳水化合物的乳酸转换</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡立杰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 胡立杰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=任南琪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,任南琪</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李永峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李永峰</a> <span> <a href="/conference-cn-27088/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第七次全国环境微生物学术研讨会 </a> <span> <span> . 2004</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311615331.html">糖类碳水化合物选择性催化转化制乳酸甲酯</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=文溢&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 文溢</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201743445.html">由含碳水化合物原料合成乳酸和乳酸烷基酯的方法</a> <b>[P]</b> . <span> 中国专利： CN103228607B </span> <span> . 2015.08.19</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120101917848.html">由含碳水化合物原料合成乳酸和乳酸烷基酯的方法</a> <b>[P]</b> . <span> 中国专利： CN103228607A </span> <span> . 2013-07-31</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130409548645.html">Synergistic formulations of functionalized copolymers and ionic liquids for dehydrated and desalted of medium, heavy and extra heavy crude oils</a> <b>[P]</b> . <span> 外国专利：  US9587182B2 </span> <span> . 2017-03-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于中，重和超重原油的脱水和脱盐的功能化共聚物和离子液体的协同配方 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130409819717.html">Synergistic formulations of functionalized copolymers and ionic liquids for dehydrated and desalted of medium, heavy and extra heavy crude oils</a> <b>[P]</b> . <span> 外国专利：  US9650577B2 </span> <span> . 2017-05-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于中，重和超重原油的脱水和脱盐的功能化共聚物和离子液体的协同配方 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130409142262.html">SYNERGISTIC FORMULATIONS OF FUNCTIONALIZED COPOLYMERS AND IONIC LIQUIDS FOR DEHYDRATED AND DESALTED OF MEDIAN, HEAVY AND EXTRA HEAVY CRUDE OILS</a> <b>[P]</b> . <span> 外国专利：  CA2773959C </span> <span> . 2017-06-27</span> </div> <p class="zwjiyix translation" 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