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Sensor based on chemical vapour deposition-grown molybdenum disulphide for gas sensing application

机译:基于化学气相沉积生长钼二硫化物的传感器

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摘要

Over the past few decades, sensors based on field-effect transistors have drawn much attention. Initially three dimensional materials were used for sensing, which were later replaced by two dimensionalmaterials because of their ease of manufacturing and large specific areas. Amongst the transition metal dichalcogenides, MoS2 has been widely used for the fabrication of sensors owing to its ability to differentiate between a charge donor and an acceptor analyte. In this work, we fabricated sensors using chemical vapour deposition grown-MoS2. MoS2 was grown on a p-Si/SiO2 substrate using Mo(CO)(6) as a precursor, the growth was carried out by the sublimation of the precursor under a flow of high purity H2S at high temperature. The aim of this work is to achieve a level of sensitivity that would enable the detection of individual gas analytes upon adsorption to the MoS2 surface. To efficiently detect individual gas analytes upon adsorption to the surface, we used interdigitated electrodes in the device architecture to increase the area of the channels for analyte adsorption. We used CO2 and O-2 gases, which acted as charge donors. A trilayer MoS2 film was examined, and the detection sensitivity for O-2 was higher in comparison to CO2. The fabricated device showed significant sensitivity up to parts per million detection level.
机译:在过去的几十年中,基于现场效应晶体管的传感器绘制了很多关注。最初三维材料用于感测,后来被两种尺寸材料所取代,因为它们的制造和大的特定区域。在过渡金属二甲基甲基化物中,由于其在充电供体和受体分析物之间的能力,MOS2已广泛用于制造传感器。在这项工作中,我们使用化学气相沉积生长-MOS2制造了传感器。使用Mo(CO)(6)作为前体在P-Si / SiO 2底物上生长MOS2,通过在高温下的高纯度H 2 S流动下升华来进行生长。这项工作的目的是达到敏感性水平,这将使在吸附到MOS2表面时能够检测单个气体分析物。为了在吸附到表面上有效地检测单个气体分析物,我们在装置架构中使用了交叉区的电极来增加分析物吸附的通道区域。我们使用了CO2和O-2气体,该气体充当了充电供体。检查三层MOS2膜,与CO2相比,O-2的检测灵敏度较高。制造的装置表现出显着的敏感性,达到百万分之一的检测水平。

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  • 来源
    《RSC Advances》 |2016年第79期|共5页
  • 作者单位

    Korea Res Inst Stand &

    Sci Ctr Vacuum Technol Daejeon 305340 South Korea;

    Korea Res Inst Stand &

    Sci Ctr Vacuum Technol Daejeon 305340 South Korea;

    Korea Res Inst Stand &

    Sci Ctr Vacuum Technol Daejeon 305340 South Korea;

    Korea Res Inst Stand &

    Sci Mat Genome Ctr Daejeon 305340 South Korea;

    Korea Res Inst Stand &

    Sci Ctr Vacuum Technol Daejeon 305340 South Korea;

    Korea Res Inst Stand &

    Sci Ctr Vacuum Technol Daejeon 305340 South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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