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首页> 外文期刊>Journal of Molecular Liquids >Study of intermolecular interactions in the ternary (1-Ethyl-3-methylimidazolium hydrogen sulfate [Emim][HSO 4]/1-Butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF 4]+D(?)fructose+water) systems using the volumetric properties at different temperatures and ambient pressure
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Study of intermolecular interactions in the ternary (1-Ethyl-3-methylimidazolium hydrogen sulfate [Emim][HSO 4]/1-Butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF 4]+D(?)fructose+water) systems using the volumetric properties at different temperatures and ambient pressure

机译:分子间相互作用的三元(1-乙基-3-甲基咪唑硫酸铵[emim] [HSO 4 ] / 1-丁基-3-甲基咪唑鎓四氟硼酸盐[ BMIM] [BF 4 “+ D(α)果糖+水)系统,在不同温度和环境压力下使用体积性质

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摘要

AbstractIn continuation of our previous works, using the density measurement, we studied some important volumetric properties such as: apparent molar volumes, standard partial molar volumes, limiting apparent molar volumes of transfer, and limiting apparent molar expansibility for the ternary (ionic liquids 1-Ethyl-3-methylimidazolium hydrogen sulfate [Emim][HSO4]/1-Butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF4]+D(?)fructose+water) atT=(293.15 to 313.15) K. By using the standard partial molar volumes and limiting apparent molar volumes of transfer, the nature of possible interactions in studied solutions are considered. Results demonstrated that for both studied ionic liquids, theVΦvalues are increased with rising concentration of ionic liquids and temperature. Also by applying the first derivative of limiting apparent molar expansibility with respect to temperature, the structure maker ability of studied ionic liquids in aqueous D(?)fructose solutions are confirmed.Highlights?Density data reported for the ternary ([Emim][HSO4] and [Bmim][BF4]+D(?)f
机译:<![cdata [ 抽象 在我们之前的工作的延续中,使用密度测量,我们研究了一些重要的体积特性,如:表观摩尔体积,标准部分摩尔体积,限制表观摩尔体积的转移,并限制了三元的表观摩尔可膨胀性(离子液体1-乙基-3-甲基咪唑硫酸铵[emim] [HSO 4 ] / 1-丁基-3-甲基咪唑鎓四氟硼酸盐[BMIM] [BF 4 “+ D(α)果糖+水)< CE:斜体> T =(293.15至313.15)K.通过使用标准部分磨牙体积和限制表观摩尔体积的转移,所研究的解决方案中可能的相互作用的性质是C. ansididered。结果证明,对于研究的两种离子液体, v φ值随着离子液体的上升浓度和温度而增加。另外,通过施加相对于温度限制表观摩尔可扩展性的第一种衍生物,确认了D(α)果糖溶液中研究了离子液体的结构制造机能力。 亮点 为期三元报告的密度数据([emim] [hso 《Journal of Molecular Liquids》 |2017年第2017期|共7页
  • 作者单位

    Department of Physical Chemistry Faculty of Chemistry Razi University;

    Department of Chemistry Faculty of Basic Science Kermanshah Branch Islamic Azad University;

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  • 正文语种 eng
  • 中图分类 理论物理学;
  • 关键词

    Volumetric properties; Density; Apparent molar volumes; Standard partial molar volumes; Limiting apparent molar volumes; Limiting apparent molar expansibility;

    机译:体积特性;密度;表观摩尔体积;标准部分磨牙体积;限制表观摩尔体积;限制表观摩尔可扩展性;
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