Effect of temperature on apparent molar properties of DBU based protic ionic liquid in aqueous and ethanolic solutions

摘要

Volumetric and ultrasonic properties of ionic liquid (IL) with molecular solvents are important parameter for elucidation of solute-solute and solute-solvent interactions occurring in solutions. In the present work, the density, p and speed of sound, u for binary solutions of the protic ionic liquid (1,8-diazabicyclo [5.4.0] undec-7-en-8-ium trifluromethane sulfonate), with molecular solvents like water and ethanol have been measured as a function of molality in temperature range (293.15 to 318.15) K and at atmospheric pressure. From the experimental data, apparent molar volume, vv, apparent molar isentropic compression, Ks,,, and limiting apparent molar expansion, E; have been calculated. Further, to understand the extent of interaction between studied IL and solvents the apparent molar properties at infinite dilution were analyzed by using Redlich-Mayer type equation. (C) 2017 Elsevier B.V. All rights reserved.