Investigation of Surface Properties for Electrolyte Solutions: Measurement and Prediction of Surface Tension for Aqueous Concentrated Electrolyte Solutions

摘要

Surface tensions for aqueous NaCl, NaBr, Nal, KCl, KBr, and KI solutions have been measured at different temperatures and different concentrations. The liquid densities and activity coefficients for electrolyte solutions are modeled accurately with the ion-based statistical associating fluid theory (SAFT2). Besides, a new surface tension prediction model on the basis of the Gibbs thermodynamic method, coupled with ion-based SAFT2 is established, which is applied to predict the surface tension of aqueous concentrated salt solutions at different concentrations and temperatures. In this model, we derived the relationship between the activity coefficient and surface tension, and the activity coefficient can be calculated by ion-based SAFT2. The model is found to give accurate prediction for the surface tension of aqueous concentrated electrolyte solutions at different concentrations and temperatures with the parameter obtained at one fixed temperature.