Ferromagnetism and diamagnetism behaviors of MgO synthesized via thermal decomposition method

摘要

MgO powders were synthesized by a thermal decomposition method which was determined by differential scanning calorimetry coupled with thermogravimetric analysis (TG/DSC). The starting material, Mg(OH)(2), was calcined at 400 degrees C, 450 degrees C and 500 degrees C for 1 h each to obtain the MgO powders. Phase composition, morphology and magnetic properties at room temperature of calcined powders were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), fourier transform infrared Spectroscopy (FTIR)and vibrating sample magnetometer (VSM), respectively. Both Mg(OH)(2) and MgO phases were found in all calcined powders. The combination of ferromagnetism and diamagnetism at room temperature of all powders were observed. It is believed to be attributed to Mg vacancies and defect in the MgO and Mg(OH)2 structures. (C) 2017 Elsevier B.V. All rights reserved.