Microstructures and immersion corrosion behavior of laser thermal sprayed amorphous Al-Ni coatings in 3.5 % NaCl solution

摘要

Amorphous Al-Ni coating with the Al and Ni mass ratios of 3:2,3:1 and 4:1 was sprayed on S355 steel of offshore platforms using a laser thermal spraying (LTS). The surface-interface morphologies, chemical element distribution, phase compositions and crystallization temperature of the obtained amorphous Al coatings were analyzed using a scanning electron microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffractometer (XRD), and differential scanning calorimetry (DSC), respectively. The im?mersion corrosion behaviors of the Al-Ni coatings in 3.5% NaCl solution for 720 h were investigated. The results shows that the Al-Ni coating is composed of Al-Fe alloy, AlCrFe_2, Ni_2MnAl and amorphous Ni-Mn-AI alloy, the metallurgical bonding is formed at the Al-Ni coating interface due to the diffusions of Al, Ni and Fe elements, and the tensile residual stress induced by LTS accelerated the crack expansion. The amorphous Al-Ni coatings have a certain amount of amorphous component at the crystallization tem?perature of-510°C. The laser thermal sprayed Al-Ni coating generates the dense oxide film immersed in NaCl solution, hindering the anion from entering, which improving the corrosion resistance of Al-Ni coatings. The electrochemical corrosion resistance of Al-Ni coatings with the Al and Ni mass ratios of 3:2 and 4:1 is better than that with the Al and Ni mass ratio of 3:1, effectively improving the corrosion resistance of S355 steel.