A coordination polymer-derived Co3O4/Co-N@NMC composite material as a Zn-air battery cathode electrocatalyst and microwave absorber

摘要

Zn-air batteries, promising energy storage equipment with high energy density, light weight and a compact structure, are a perfect power source for electric vehicles. For a Zn-air battery, the activity of the air cathode electrocatalyst plays an important role in its performance. Here, employing a coordination polymer as a precursor, a composite material built from Co3O4 and Co-N active centres with nitrogen-doped mesoporous carbon as a matrix has been synthesized successfully. This composite material possesses outstanding activity and stability in the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) processes. It possesses a small half-wave potential (ORR1/2 = 0.786 V) and low overpotential (OER10 = 1.575 V) for the ORR and OER, respectively. With this composite material as an air cathode electrocatalyst, a rechargeable Zn-air battery was assembled successfully. During the discharge process, the maximum power density of this Zn-air battery is 122 mW cm(-2) at 0.76 V. The specific capacity of this battery is 505 mA h g(-1) at 25 mA cm(-2). The voltage gap between the charge and discharge processes is only 0.744 V at 10 mA cm(-2) and 1.308 V at 100 mA cm(-2). This rechargeable battery also shows promising stability after long-term charge-discharge experiments. Furthermore, the composite material also exhibits outstanding microwave adsorption properties. Its maximum reflection loss (RL) arrives at -13.9 dB with a thickness of only 1.0 mm. Thus, we find that coordination polymers are an ideal precursor for Zn-air battery cathode electrocatalysts and microwave absorbers.