Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds

【24h】

Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds

机译：用银（I）离子的三元含量的金属 - 金属键形成，得到含有四个Pt-Ag键的庚烷群

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

团队文献服务 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

An N-heterocyclic carbene triplatinum complex with two triply bridging sulfide ligands reacts with a silver(i) salt and affords a heptanuclear complex. X-ray crystallographic analysis revealed that a silver(i) ion connects two triplatinum complexes with one of the three Pt-Pt bonds of each triplatinum unit.

机译：与两个三桥桥硫化物配体的N-杂环卡蛋白复合物与银（I）盐反应，得到庚烷络合物。 X射线结晶分析显示，银（I）离子与每个三份子单位的三个Pt-Pt键之一连接两倍。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry 》 |2020年第23期| 共4页
作者

展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学 ; 无机化学 ;
关键词

相似文献

外文文献
中文文献
专利

1. Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds [J] . Dalton transactions: An international journal of inorganic chemistry . 2020 ,第23期

机译：用银（I）离子的三元含量的金属 - 金属键形成，得到含有四个Pt-Ag键的庚烷群
2. Ir _3Co _6 and Co _3Fe _3 dithiolene cluster complexes: Multiple metal-metal bond formation and correlation between structure and internuclear electronic communication [J] . Tsukada S., Shibata Y., Sakamoto R., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012 ,第3期

机译：Ir _3Co _6和Co _3Fe _3二硫代簇簇配合物：多种金属-金属键形成以及结构与核间电子通信之间的相关性
3. A dimolybdenum complex with an alkyne ligand parallel to the metal-metal bond: synthesis, structure and cluster formation reactions of [Mo-2(mu-eta(1),eta(1)-C2Ph2)(mu-S)(mu-SPri)(2)Cp-2] [J] . Adams H., Mountford P., Patel R., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2001 ,第18期

机译：具有与金属-金属键平行的炔基配体的二钼配合物：[Mo-2（mu-eta（1），eta（1）-C2Ph2）（mu-S）（mu- SPri）（2）Cp-2]
4. Synthesis and Property of a Heptanuclear Complex Bearing TwoTriplatinum Units Bridged by a Silver(I) Ion [C] . Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka 日本化学会春季年会 . 2020

机译：银（I）离子桥接桥桥轴承骨核络合物的合成及性能
5. Mechanisms of electron transfer and hydrogen activation in selected triruthenium clusters with multiple bridging ligands. Part I. The attenuation of radical reactivity in triruthenium trihydrido(alkylidyne) clusters. Electrochemistry and kinetics of decomposition of the 47-electron cluster radical, via a disproportionation path. Part II. The activation of molecular hydrogen at transition metal centers via kinetics and mechanism of reversible oxidative addition of hydrogen across the metal-metal bond of (mu-hydrogen)(2)Ruthenium(3)(Carbon monoxide)(8)(mu-phosphorus(t-BU)(2))(2). [D] . Bierdeman, David John. 2000

机译：具有多个桥联配体的选定三钌簇中电子转移和氢活化的机理。第一部分。三氢三钌（亚烷基）簇中自由基反应性的减弱。通过歧化路径分解47电子簇自由基的电化学和动力学。第二部分通过（mu-hydrogen）（2）钌（3）（一氧化碳）（8）（mu-phosphorus（）的金属-金属键上氢的可逆氧化加成反应的动力学和机理激活过渡金属中心的分子氢t-BU）（2））（2）。
6. Many Mg–Mg bonds form the core of the Mg16Cp*8Br4K cluster anion: the key to a reassessment of the Grignard reagent (GR) formation process? [O] . T. Kruczyński, F. Henke, M. Neumaier, 2016

机译：许多Mg–Mg键形成Mg16Cp * 8Br4K簇阴离子的核心：重新评估格氏试剂（GR）形成过程的关键吗？
7. Formation of a Dithiophosphinate Ligand Ph2PS2 by Sulfur Insertion into the Metal-Phosphido Bond on Heterobimetallic Phosphido-Bridged Complex Cp(CO)2{siComponents}amp;tie;0{siComponents}W(m-PPh2){siComponents}amp;tiex;0{siComponents}Mo(CO)5: A Rare Example of a Neutral Six-Electron Mixed-Metal Cluster with a Mo2WS4 Core [O] . -1

机译：通过硫插入金属 - 磷酸酯粘合剂上的二硫代磷酸二磷酸酯配体pH2PS2在杂二磷酸酯桥络合物CP（CO）2的粘合剂中; LT;系; 0 {Sicomponents} GT; W（M-PPH2）{Sicomponents} amp; tiex; 0 {sicomponents} mo（co）5：具有mo2ws4芯的中性六电子混合金属簇的罕见实例

Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds

摘要

著录项

相似文献

相关主题

期刊订阅