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Copper-Catalyzed Oxidative Perfluoroalkylation of Aryl Boronic Acids Using Perfluoroalkylzinc Reagents

机译:使用全氟烷基锌试剂的铜催化芳基硼酸的氧化全氟烷基化

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摘要

An efficient and synthetically convenient method for copper-catalyzed cross-coupling of aryl boronic acids with perfluoroalkyl zinc reagents has been described. The reaction proceeds under mild reaction conditions with a high efficiency and broad substrate scope and provides a general access to perfluoroalkylated arenes, which are of interest in life and materials science.
机译:已经描述了具有全氟烷基锌试剂的芳基硼酸的铜催化交叉偶联的有效和合成方便的方法。 反应在温和的反应条件下进行,具有高效率和宽的基材范围,并提供对全氟烷基化的竞争的一般性,这对生活和材料科学感兴趣。

著录项

  • 来源
    《The Journal of Organic Chemistry》 |2018年第1期|共6页
  • 作者单位

    School of Chemistry and Chemical Engineering Hefei University of Technology 193 Tunxi Road Anhui 230000 People’s Republic of China;

    School of Biological and Medical Engineering Hefei University of Technology 193 Tunxi Road Anhui 230000 People’s Republic of China;

    School of Chemistry and Chemical Engineering Hefei University of Technology 193 Tunxi Road Anhui 230000 People’s Republic of China;

    School of Chemistry and Chemical Engineering Hefei University of Technology 193 Tunxi Road Anhui 230000 People’s Republic of China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 有机化学;
  • 关键词

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