Methane Oxidation in a Landfill Cover Soil under Conditions of Diffusive and Advective Flux, Assessed by In-Situ and Ex-Situ Methods

摘要

The cover soil of a non-sanitary municipal solid waste landfill was analyzed with respect to methane oxidation efficiency, oxidation rates, bottom and surface fluxes, thereby comparing hotspots of gas emission with non-emitting locations. The range ofmethods included in-situ approaches (gas push-pull tests, carbon mass balance, stable isotope fractionation) and ex-situ methods (batch testing in the laboratory). The nature of the gas exchange through the cover soil was most relevant for the observedoxidation efficiency. At hotspots, gas transport was predominantly ad-vective, resulting in bottom fluxes as high as 1,028 g CH4 m2 d"1, restricting methane oxidation to the upper crust of the soil due to impeded ingress of atmospheric oxygen. At these locations, significant emissions were observed, but also high oxida-tion rates of up to 240 g m2 d"1. Contrastingly, over the greatest part of the landfill area gas transport through the cover was diffusive with usually complete methane oxidation and subsequently no emissions. In all cases, oxidation efficiency and the soil depths participating in the process were tightly related to the extent of soil aeration, suggesting the seasonal variation in soil moisture as a key variable. Batch testing in the laboratory reflected the previous exposure of the soil to landfill gasrather than the soil's inherent oxidation potential. Compared to the in situ potential, soil sampling, pre-treatment and incubation in the laboratory yielded significantly lower values for the oxidation potential. For the given landfill, the carbon massbalance seemed to provide the easiest and most correct assessment for the quantification of methane fluxes to, through and from the cover soil.