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Applied homogeneous catalysis by organometallic complexes

机译:有机金属配合物的均相催化

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The overview describes the industrial application of homogeneous catalysts for the chemical industry. In the first part, some theoretical background is given on organometallic complexes and homogeneous catalysis followed by a description of the prerequisites and current problems for their industrial application. Selected examples of industrially useful catalysts for the manufacture of bulk and fine chemicals are described for the following transformations: enantioselective hydrogenation, isomerization and epoxidation for producing enantiomerically enriched products; the application of the Heck reaction, the Suzuki and Sonogashira coupling and the carbonylation reaction for the manufacture of intermediates for pharmaceuticals and agrochemicals; the application of the carbonylation technology for the large-scale production of acetic acid and butyraldehydes. In the last part, future prospects of the industrial application of homogeneous catalysis are briefly discussed. [References: 34]
机译:概述描述了均相催化剂在化学工业中的工业应用。在第一部分中,给出了有关有机金属配合物和均相催化的一些理论背景,随后描述了其工业应用的前提条件和当前问题。描述用于以下转化的工业上有用的催化剂的生产实例,所述催化剂用于制造本体和精细化学品:对映选择性氢化,异构化和环氧化,用于生产对映异构体富集的产物; Heck反应,Suzuki和Sonogashira偶联以及羰基化反应在制药和农用化学品中间体生产中的应用;羰基化技术在大规模生产乙酸和丁醛中的应用。在最后一部分中,简要讨论了均相催化的工业应用前景。 [参考:34]

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