Platinum(II) coordination compound with 4 '-[4-(dimethylamino)phenyl]-2,2 ':6 ',2 ''-terpyridine - The new insight into the luminescence behavior and substituent effect

摘要

{PtCl[4'-(4-NMe2)-Ph-terpy-kappa N-3]}BPh4 center dot CH3CN (1) was synthesized and its structural, electrochemical and photophysical properties were characterized in comparison to previously described systems of [PtCl(4'-Ph-terpy-kappa N-3)](+)and [PtCl(4'-NMe2-terpy-kappa N-3)](+) to determine again the significance of the appropriate design of substituent in case of luminescence behavior of transition metal complex. The molecular formula of compound was confirmed by.