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Modification of coal tar pitch by chemical method to reduce benzo(a)pyrene

机译:化学方法改性煤焦油沥青以还原苯并(a)py

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摘要

Coal tar pitch (CTP) comprises mainly polycyclic aromatic hydrocarbons, some of which are carcinogenic in nature. Among these, benzo(a)pyrene (B(a)P) is one of the most prominently reported carcinogens and its presence in CTP is a cause of concern for environmentaiists. B(a)P gets released into the atmosphere during processing of CTP for various applications and is the cause of adverse effects on human health and the environment. In the present study, CTP has been modified using different modifiers to reduce the content of B(a)P. This involves not only the analysis for content of B(a)P in CTP by HPLC, but also deals with the several physicochemical properties before and after modification of CTP. It has been observed that the B(a)P content can be reduced almost to the extent of 80% by chemical modification. On comparing the physico-chemical properties of CTP before and after modification, it has been observed that there is no noticeable change. Thus, modified CTP can be effectively used for various applications, without the potential hazards of B(a)P.
机译:煤焦油沥青(CTP)主要包含多环芳烃,其中一些具有致癌性。其中,苯并(a)((B(a)P)是最著名的致癌物质之一,其在CTP中的存在引起了环保主义者的关注。在各种用途的CTP加工过程中,B(a)P释放到大气中,并且是对人体健康和环境造成不利影响的原因。在本研究中,已使用不同的改性剂对CTP进行了改性,以减少B(a)P的含量。这不仅涉及通过HPLC分析CTP中B(a)P的含量,而且涉及修饰CTP之前和之后的几种物理化学性质。已经观察到,通过化学修饰,B(a)P含量几乎可以降低到80%的程度。在比较改性前后的CTP的理化性质时,已观察到没有明显的变化。因此,修饰的CTP可以有效地用于各种应用,而没有B(a)P的潜在危害。

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