Blast furnace slag-Mg(OH)(2) cements activated by sodium carbonate

摘要

The structural evolution of a sodium carbonate activated slag cement blended with varying quantities of Mg(OH)(2) was assessed. The main reaction products of these blended cements were a calcium-sodium aluminosilicate hydrate type gel, an Mg-Al layered double hydroxide with a hydrotalcite type structure, calcite, and a hydrous calcium aluminate phase (tentatively identified as a carbonate-containing AFm structure), in proportions which varied with Na2O/slag ratios. Particles of Mg(OH)(2) do not chemically react within these cements. Instead, Mg(OH)(2) acts as a filler accelerating the hardening of sodium carbonate activated slags. Although increased Mg(OH)(2) replacement reduced the compressive strength of these cements, pastes with 50 wt% Mg(OH)(2) still reached strengths of approximate to 21 MPa. The chemical and mechanical characteristics of sodium carbonate activated slag/Mg(OH)(2) cements makes them a potentially suitable matrix for encapsulation of high loadings of Mg(OH)(2)-bearing wastes such as Magnox sludge.