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Experimental Formulation of Photonic Crystal Properties for Hierarchically Self-Assembled POSS–Bottlebrush Block Copolymers

机译:层级自组装POSS-瓶装嵌段共聚物光子晶体性能的实验制剂

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摘要

机译:<![CDATA [roblike“poss-botherbrush嵌段共聚物”(possbbcps)嵌段中的嵌段和无定形聚合物移植物中的结晶多面体寡聚体蛋白(poss)侧链,以产生一维(1d)光子晶体(PC) 。 3-(12 - ( CIS -5-降冰片烯 - EXO -2,3-二羧酰亚胺)十二烷酰基脱氨基)丙基癸基丁基( Nb-a16-poS,m_(a))和 exo -5-降冰片烯-2-羰基 - 末端聚(甲基丙烯酸苄基)(甲基丙烯酸苄基,M_(b))中使用顺序开环复分解聚合,得到聚合金[3-(12 - ( CIS - 5-降冰片烯 - EXO -2,3-二羧基咪唑)十二烷酰基氨基)丙基甲基二丁基POSS] - 嵌段 - 聚( EXO -5-降冰片烯-2-羰基酯 - 移植物 - 苄基甲基丙烯酸苄基) , p(nb-a16-poss) - b -p(nb- -bzma)s,具有良好调制的嵌段组合物( f _(a)= 34,50和67wt%)和总体聚合度(DP = 323-939)。 p(Nb-a16-poss) - b -p(nb- g -bzma)的分层自组装以形成高度有序的具有周期性板阵列的1D PC膜,其可以反射特定波长的可见光。它们的反射带宽,反射功能和峰值反射波导(λ_(峰))的范围大大依赖于嵌段组合物。基于层状薄膜 p(Nb-a16-poss) - b> -p(Nb- g -bzma)s的1d pc膜证明λ_(峰值)的萌发能力作为初始聚合参数的线性函数([m] _(0)/ [i] _(0))。]>

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  • 来源
    《Macromolecules》 |2018年第9期|共9页
  • 作者单位

    School of Materials Science and Engineering and Grubbs Center for Polymers and Catalysis Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering and Grubbs Center for Polymers and Catalysis Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering and Grubbs Center for Polymers and Catalysis Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering and Grubbs Center for Polymers and Catalysis Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering and Grubbs Center for Polymers and Catalysis Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering and Grubbs Center for Polymers and Catalysis Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

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  • 正文语种 eng
  • 中图分类 高分子化学(高聚物);
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