首页> 外文期刊>Macromolecules >Synthesis of Hard–Soft–Hard Triblock Copolymers, Poly(2-naphthyl glycidyl ether)-block-poly[2-(2-(2-methoxyethoxy)ethoxy)ethyl glycidyl ether]-block-poly(2-naphthyl glycidyl ether), for Solid Electrolytes
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Synthesis of Hard–Soft–Hard Triblock Copolymers, Poly(2-naphthyl glycidyl ether)-block-poly[2-(2-(2-methoxyethoxy)ethoxy)ethyl glycidyl ether]-block-poly(2-naphthyl glycidyl ether), for Solid Electrolytes

机译:硬质软硬三嵌段共聚物的合成,聚(2-萘基缩水甘油醚) - 嵌段 - 聚氯乙烯[2-(2-(2-(2-(2-(2-(2-(2-(2-甲氧乙氧基)乙氧基)乙基缩水甘油醚] - 嵌段 -poly(2-萘基缩水甘油醚),用于固体电解质

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摘要

机译:<![CDATA [硬 - 软 - 硬基于聚(环氧乙烷)(PEO),聚三嵌段共聚物(2-萘基缩水甘油基醚) - 的块 - 聚[2-(2-(2-甲氧基乙氧基)乙氧基)乙基缩水甘油醚] - 的块 - 聚(2-萘基缩水甘油基醚)(PNG-PTG-PNG图像),通过2-依次开环聚合(合成2-(2-甲氧基乙氧基)乙氧基)乙基缩水甘油醚和2-萘基使用由磷腈碱催化的引发剂双向缩水甘油醚。四PNG-PTG-的PNG有不同的块组合物(˚F_(重量,PNG)= 9.2-28.6重量%),控制的分子量(中号_(N)= 23.9-30.9 kDa的),并缩小分散度(?= 1.11-1.14)。大部分的PNG-PTG-PNG电解质在室温下具有高得多的立〜(+)导率比一个PEO电解质的(6.54×10〜(-7)s厘米〜(-1))。 Eespecially,李〜PNG_的(+)电导率(18)-PTG_(107)-PNG_(18)的电解质(9.5×10〜(-5)s厘米〜(-1)的˚F_(重量, PNG)= 28.6%(重量))是可比较的PTG电解质之一(1.11×10〜(-4)s厘米〜(-1))。 PNG-PTG-PNG电解质的锂〜(+)传导性密切相关于由微相分离成软PTG和硬PNG域形成高效栗〜(+)传输信道。]]>

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  • 来源
    《Macromolecules》 |2018年第6期|共9页
  • 作者单位

    School of Materials Science and Engineering Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    Division of Applied Chemistry Faculty of Engineering and Graduate School of Chemical Sciences and Engineering Hokkaido University Sapporo 060-8628 Japan;

    Division of Applied Chemistry Faculty of Engineering and Graduate School of Chemical Sciences and Engineering Hokkaido University Sapporo 060-8628 Japan;

    School of Materials Science and Engineering Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    School of Materials Science and Engineering Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

    Division of Applied Chemistry Faculty of Engineering and Graduate School of Chemical Sciences and Engineering Hokkaido University Sapporo 060-8628 Japan;

    School of Materials Science and Engineering Gwangju Institute of Science and Technology (GIST) 123 Cheomdangwagi-ro Buk-gu Gwangju 61005 Republic of Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 高分子化学(高聚物);
  • 关键词

  • 入库时间 2022-08-19 17:15:17

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