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Characterization and adsorption capacity of potassium permanganate used to modify activated carbon filter media for indoor formaldehyde removal

机译:高锰酸钾的表征和吸附能力用于改性活性炭过滤介质的室内甲醛去除

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This study examined the effect of potassium permanganate (KMnO~(4))-modified activated carbon for formaldehyde removal under different face velocities and different initial formaldehyde concentrations in building environment. We chose the coconut shell activated carbon due to their high density and purity. Moreover, they have a clear environmental advantage over coal-based carbons, particularly in terms of acidification potential. The chemical properties were characterized by FTIR to show the functional groups, EDS to calculate each component of their energy bands to know how the ratio is. Also, the morphology of the surface was examined with scanning electron microscopy (SEM). The BET determines specific surface area, pore size, and pore volume. It was found that where the initial formaldehyde concentration and the face velocity are low, adsorption capacity is high. The adsorption isotherms of formaldehyde on modified activated carbon are well fitted by both Langmuir and Freundlich equations. The rate parameter for the pseudo-first-order model, pseudo-second-order model, and intraparticle diffusion model was compared. The correlation coefficient of pseudo-second-order kinetic model (0.999?>? R _(2)?>?0.9548) is higher than the coefficient of pseudo-first-order kinetic model (0.5785?
机译:该研究检测了高锰酸钾(KMnO〜(4)) - 改性活性炭在不同面速度下除去的甲醛去除的影响,以及建筑环境中不同的甲醛浓度。我们由于它们的高密度和纯度而选择了椰壳活性炭。此外,它们在煤炭的碳上具有明显的环境优势,特别是在酸化潜力方面。通过FTIR表征化学性质以显示官能团,EDS计算其能带的每个组分以了解该比率是如何。而且,用扫描电子显微镜(SEM)检查表面的形态。该投注决定了比表面积,孔径和孔体积。发现初始甲醛浓度和面速度低,吸附能力高。通过Langmuir和Freundlich方程,甲醛对改性活性炭的吸附等温线很好地安装得很好。比较了伪第一阶模型,伪二阶模型和脊髓正版扩散模型的速率参数。伪二阶动力学模型的相关系数(0.999?>ΔR_(2)?0.9548)高于伪一阶动力学模型的系数(0.5785?<?r _(2)? <?0.8755)和粒子分散模型(0.9752〜_(2)?<?0.9898)。因此,伪二阶动力学模型更恰当地讨论该试验中的吸附动力学,并且改性活性炭吸附过程的总速率似乎受到多于一个步骤的影响,这是粒前扩散模型和膜。扩散。

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