Spectral behavior of sulfides in simulated daytime surface conditions of Mercury: Supporting past (MESSENGER) and future missions (BepiColombo)

摘要

To detect the mineral diversity of a planet's surface, it is essential to study the spectral variations over a broad wavelength range at relevant simulated laboratory conditions. The MESSENGER (Mercury Surface, Space Environment, Geochemistry, and Ranging) mission to Mercury discovered that irrespective of its formation closest to the Sun, Mercury is richer in volatiles than previously expected. This is especially true for sulfur (S), with an average abundance of 4 wt%. It has been proposed that sulfur in the interior of Mercury can be brought to the surface through volcanic activity in the form of sulfides as slag deposits in Mercury hollows and pyroclastic deposits. However, comprehensive spectral library of sulfide minerals measured under vacuum conditions in a wide spectral range (0.2-100 mu m) was lacking. This affects the detectability and understanding of the distribution, abundance, and type of sulfides on Mercury using remote-sensing spectral observations. In the case of Mercury, the effect of thermal weathering affecting the spectral behavior of these sulfides must be studied carefully for their effective detection. In this study, we present a spectral library of synthetic sulfides including MgS, FeS, CaS, CrS, TiS, NaS, and MnS. For each sample, we performed emissivity measurements in the thermal infrared range (TIR: similar to 7-14 mu m) for sample temperatures from 100 degrees C-500 degrees C, covering the daytime temperature cycle on Mercury's surface. In addition, for each sample we measured the spectral reflectance of fresh and thermally processed sulfides over a wide spectral range (0.2-100 mu m) and at four different phase angles, 26 degrees, 40 degrees, 60 degrees, 80 degrees. This spectral library facilitates the detection of sulfides by past and future missions to Mercury by any optical spectrometer of any spectral range. Specifically, the emissivity measurements in this study will support the Mercury Radiometer and Thermal Imaging Spectrometer