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Synthesis, Structure and Antioxidant Activity of Mixed Ruthenium(III) Benzoyl Pyridine Complex

机译:混合钌(III)苯甲酰基吡啶复合物的合成,结构和抗氧化活性

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摘要

A new ruthenium arsine complex was prepared by reacting equimolar ratio of [RuBr3(AsPh3)3] and 2-benzoyl pyridine. It was characterized by microanalysis, FT-IR and single crystal X-ray diffraction studies. X-ray diffraction data showed the distorted octahedral geometry of the complex. The pyridine nitrogen and carbonyl oxygen of the ligand coordinated with the metal center. Antioxidant activity of the complex was analyzed using different assays, which manifested significant activity. It has been found that a newly synthesized complex possessed better antioxidant activity than the ligand and precursor complex.
机译:通过使[rubr3(沥青3)3]和2-苯甲酰基吡啶的等摩尔比反应来制备新的芳烃复合物。 它的特征在于微观分析,FT-IR和单晶X射线衍射研究。 X射线衍射数据显示复合物的扭曲八面体几何形状。 配体配体的吡啶氮气和羰基氧与金属中心配位。 使用不同的测定分析复合物的抗氧化活性,表现出显着的活性。 已经发现,新合成的复合物具有比配体和前体复合物更好的抗氧化活性。

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