Synthesis and luminescence properties of ternary complexes of Sm _x Tb_(1-x) (TTA)_3Phen nanoparticles and their surface modification

摘要

A series of Sm _x Tb_(1-x) (TTA)_3Phen (x = 1.0, 0.9, 0.7, 0.5, 0.3, 0.1, 0) complexes was synthesized by wet chemical method and characterized using Fourier transform infrared spectroscopy and fluorescence spectroscopy. The IR absorption spectra indicate that α-thenoyltrifluoroacetone was coordinated to the rare earth ions and that chemical bonds were formed between rare earth ions and the nitrogen atoms in 1,10-Phenanthroline (Phen). The fluorescence spectra of the complexes indicate that the emission intensity of Sm3+ was enhanced by the addition of substitutive Tb~(3+). These data show that not only the ligands (TTA and Phen) but also Tb~(3+) could absorb and transmit energy to Sm ~(3+) in the complexes. Formation of dual-core complexes appears to be responsible for co-fluorescence, which can greatly promote the illuminant ability of Sm (TTA)3Phen complex. After further encapsulation by SiO_2, the Sm _x Tb_(1-x) (TTA) _3Phen@SiO_2 core-shell structure was very stable to UV light.