Effect of titanium carbide coating on the microstructure and thermal conductivity of short graphite fiber/copper composites

摘要

Graphite fiber-Cu composites have drawn much attention in electronic packaging due to its excellent machinability and thermal properties. However, the weak interface bonding between graphite fiber and copper resulted in low thermo-mechanical properties of composites. In this work, a titanium carbide coating with thickness of 0.1 μm or 1 μm was synthesized on the surface of graphite fiber through molten salts method to strengthen interfacial bonding. The enhanced composites present 24-43 % increase in thermal conductivity and achieve the thermal conductivity of 330-365 W m~(-1) K~(-1) as well as the coefficient of thermal expansion of 6.5 × 10~(-6)-14 × 10~(-6) K~(-1). A Maxwell-Garnett effective medium approach on the anisotropic short fiber reinforcement with interfacial thermal resistance was established. The obtained enhancement was in good agreement with the estimates. The results suggest that the major factor that influences the thermal conductivities is not the interfacial thermal resistance but the low thermal conductivity of fiber in transversal direction when a well interfacial bonding is obtained.