Metallicity of Ca2Cu6P5 with single and double copper-pnictide layers

摘要

We report thermodynamic and transport properties, and also theoretical calculations, for Cu-based compound Ca2Cu6P5 and compare with CaCu2-delta P2. Both materials have layers of edge-sharing copper pnictide tetrahedral CuP4, similar to Fe-As and Fe-Se layers (with FeAs4, FeSe4) in the iron-based superconductors. Despite the presence of this similar transition-metal pnictide layer, we find that both Ca2Cu6P5 and CaCu2-delta P2 have temperature-independent magnetic susceptibility and show metallic behavior with no evidence of either magnetic ordering or superconductivity down to 1.8 K CaCu2-delta P2 is slightly off-stoichiometric, with delta = 0.14. Theoretical calculations suggest that unlike Fe 3d-based magnetic materials with a large density of states (DOS) at the Fermi surface, Cu have comparatively low DOS, with the majority of the 3d spectral weight located well below Fermi level. The room-temperature resistivity value of Ca2Cu6P5 is only 9 mu Omega-cm, due to a substantial plasma frequency and an inferred electron-phonon coupling lambda of 0.073 (significantly smaller than that of metallic Cu). Also, microscopy result shows that Cu-Cu distance along the c-axis within the double layers can be very short (2.5 angstrom), even shorter than metallic elemental copper bond (2.56 angstrom). The value of d rho/dT for CaCu2-delta P2 at 300 K is approximately three times larger than in Ca2Cu6P5, which suggests the likelihood of stronger electron-phonon coupling. This study shows that the details of Cu-P layers and bonding are important for their transport characteristics. In addition, it emphasizes the remarkable character of the DOS of '122' iron-based materials, despite much structural similarities. Published by Elsevier B.V.