Enhanced green upconversion by controlled ceramization of Er3+-Yb3+ co-doped sodium niobium tellurite glass-ceramics for low temperature sensors

摘要

Tellurite based glasses are well-known for their upconversion properties besides having a disadvantage of low mechanical strength dragging them away from practical applications. The present work deals with preparation of sodium niobium tellurite (SNT) glasses using melt quenching method, in which small quantities of boron and silicon in the form of oxides are added to improve their mechanical properties. Controlled heat treatment is performed to ceramize the prepared glasses based on the thermal data given by DTA. XRD and SEM profiles of the glass-ceramics which confirmed the formation of crystalline monoclinic Sodium Tellurium Niobium Oxide (Na1.4Nb3Te4.9O18) phase (JCPDS card No. 04-011-7556). Upconversion measurements in the visible region were made for the prepared Er3+-Yb3+ co-doped glasses and glass-ceramics with 980 nm laser excitation varying the laser power and concentration of Er3+ ions. Results showed that the upconversion luminescence intensity was enhanced by ten times in SNT glass-ceramics compared to that in the SNT glasses. Decay curves give evidence of high performance of glass-ceramics compared to glasses due to ceramization and structural changes. Temperature dependent visible upconversion was performed to test the ability of efficient SNT glass-ceramic at low temperatures and variation of upconversion intensities was studied. (C) 2014 Elsevier B.V. All rights reserved.