Evolution of magnesium during reactive milling under hydrogen atmosphere with crystallitic carbon as milling aid

摘要

This paper is concerned with the changes of morphology, crystal structure and hydrogen storage properties of magnesium during reactive milling under hydrogen atmosphere with crystallitic carbon, which is prepared from anthracite coal by demineralization and carbonization, as milling aid. Experiments show that β-MgH_2 of tetrahedral crystal structure with particle size of 20-60 nm and geometric shape of oblique hexagonal prism predominates in the material from 3 h of milling under 1 MPa H_2. Besides, there is γ-MgH_2 of orthorhombic crystal structure in the materials from milling. The Mg particles from MgH_2 dehydriding take the shape of right hexagonal prism. The carbon can prevent Mg particles from coalescing into big bulk during heating for hydrogen releasing. The endothermic peak of y-MgH_2 is 53 °C lower than that of p-MgH_2 in the materials from 10 to 20 h of milling, and its heat absorption for dehydriding is 18 kJ/mol H_2 lower than that of β-MgH_2.