Improvement of the electrochemical performance of LiMn_2O_4 cathode active material by lithium borosilicate (LBS) surface coating for lithium-ion batteriesHalil Sahan*, Hiiseyin Goktepe, Saban Patat, Ahmet OlgenDepartment of Chemistry, Faculty of Science, Erciyes University, Tolas St., 38039 Kayseri, Turkey

摘要

The LBS coating on the surface of spinel LiMn_2O_4 powder was carried out using the solid-state method, followed by heating at 425 °C for 5 h in air. The powder X-ray diffraction pattern of the LBS-coated spinel LiMn_2O_4 showed that the LBS coating medium was not incorporated in the spinel bulk structure. The SEM result showed that the LBS coating particles were homogeneously distributed on the surface of the LiMn_2O_4 powder particles. The effect of the lithium borosilicate (LBS) coating on the charge-discharge cycling performance of spinel powder (LiMn_2O_4) was studied in the range of 3.5-4.5 V at 1C. The electrochemical results showed that LBS-coated spinel exhibited a more stable cycle performance than bare spinel. The capacity retention of LBS-coated spinel was more than 93.3% after 70 cycles at room temperature, which was maintained at 71.6% after 70 cycles at 55 °C. The improvement of electrochemical performance may be attributed to suppression of Mn2* dissolution into the electrolyte via the LBS glass layer.