首页> 外文期刊>Journal of Applied Polymer Science >Preparation of poly(ε-caprolactone)/poly(ε-caprolactone-co- lactide) (PCL/PLCL) blend filament by melt spinning
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Preparation of poly(ε-caprolactone)/poly(ε-caprolactone-co- lactide) (PCL/PLCL) blend filament by melt spinning

机译:熔融纺丝法制备聚(ε-己内酯)/聚(ε-己内酯-共-丙交酯)(PCL / PLCL)共混丝

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摘要

Poly(ε-caprolactone)/poly(ε-caprolactone-co-lactide) (PCL/PLCL) blend filaments with various ratios of PCL and PLCL were prepared by melt spinning. The effect of PLCL content on the physical properties of the blended filament was investigated. The melt spinning of the blend was carried out and the as spun filament was subsequently subjected to drawing and heat setting process. The addition of PLCL caused significant changes in the mechanical properties of the filaments. Crystallinity of blend decreased with the addition of PLCL as observed by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). Scanning electron microscopy (SEM) revealed that the fracture surface becomes rougher at higher PLCL content. It may be proposed that PCL and PLCL show limited interaction within the blend matrix.
机译:通过熔融纺丝制备具有不同比例的PCL和PLCL的聚(ε-己内酯)/聚(ε-己内酯-丙交酯)(PCL / PLCL)共混丝。研究了PLCL含量对混合长丝物理性能的影响。进行共混物的熔融纺丝,然后将纺成的长丝进行拉伸和热定型过程。 PLCL的加入导致细丝的机械性能发生显着变化。 X射线衍射(XRD)和差示扫描量热法(DSC)观察到,添加PLCL会降低共混物的结晶度。扫描电子显微镜(SEM)显示,PLCL含量较高时,断口表面变得更粗糙。可以建议PCL和PLCL在混合矩阵内显示有限的交互作用。

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