Reinforcement of Polyurethane/Epoxy Interpenetrating Network Nanocomposites with an Organically Modified Palygorskite

摘要

An organophilic palygorskite (o-PGS) prepared by the treatment of natural palygorskite with hexadecyl trimethyl ammonium bromide was incorporated into interpenetrating polymer networks (IPNs) of polyurethane (PU) and epoxy resin (EP), and a series of PU/EP/clay nanocomposites were obtained by a sequential polymeric technique and compression-molding method. X-ray diffraction and scanning electron microscopy analysis showed that adding nanosize o-PGS could promote the compatibility and phase structure of PU/EP IPN matrices. Tensile testing and thermal analysis proved that the mechanical and thermal properties of the PU/EP IPN nanocomposites were superior to those of the pure PU/EP IPN. This was attributed to the special fibrillar structure of palygorskite and the synergistic effect between o-PGS and the IPN matrices. In addition, the swelling behavior studies indicated that the crosslink density of PU/EP IPN gradually increased with increasing o-PGS content. The reason may be that o-PGS made the chains more rigid and dense. As for the flame retardancy, the PU/EP nanocomposites had a higher limiting oxygen index than the pure PU. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 31503162, 2009