Effects of Chain Lengths, Molecular Orientation, and Functional Groups of Thiols Adsorbed onto CF Surface on Interfacial Properties of CF/Epoxy Composites

摘要

In this article, a new treatment method based on molecular self-assembly on carbon fiber (CF) surface was proposed for obtaining a controlled interface between CF and epoxy matrix in composite system. To form the controlled interfacial region, the surfaces of CF were first metallized by electroless Ag plating, then were reacted with a series of thiols (alkanethiols, aromatic thiol, and heterocyclic thiol) to form self-assembly (SA) films, which further reacted with epoxy resin to generate a strong adhesion interface. The structure and composition of untreated and treated CF surface were investigated by surface-enhanced Raman scattering spectroscopy (SERS) and X-ray photoelectron spectroscopy (XPS), respectively. SERS study showed that thiols chemisorbed on Ag-plated CF in the form of thiolate species via the strong SAAg coordinative bond. Moreover, adsorbate orientation of thiols SA films on Ag-plated CF surfaces was revealed on the basis of SERS selection rules. The XPS study further confirmed the well organized alignment and the chemisorption of thiols. To understand the interfacial adhesion mechanism, the interfacial shear strength of CF/epoxy microcomposites was evaluated by the microbond technique. The results showed that among the parameters such as chain lengths, molecular orientation, and types of functional groups, the chemical nature of functional groups is most important for the improvement of interfacial properties in CF/epoxy composites.