Morphology and Mechanical Properties of Injection-Molded Ultrahigh Molecular Weight Polyethylene/Polypropylene Blends and Comparison with Compression Molding

摘要

The mechanical properties and morphology of UHMWPE/PP(80/20) blend molded by injection and compression-mol ding were investigated comparatively. The results showed that the injection-molded part had obviously higher Young's modulus and yield strength, and much lower elongation at break and impact strength, than compression-molded one. A skin-core structure was formed during injection molding in which UHMWPE particles elongated highly in the skin and the orientation was much weakened in the core. In the compression-molded part, the phase morphology was isotropic from the skin to the core section. The difference in consolidation degree between two molded parts that the compression molded part consolidated better than the injection one was also clearly shown. In addition, compositional analysis revealed that there was more PP in the skin than core for the injection-molded part, whereas opposite case occurred to the compression-molded one. All these factors together accounted for the different behavior in mechanical properties for two molded parts. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 890-898, 2009