Relationship between processing method and microstructural and mechanical properties of poly(ethylene terephthalate)/short glass fiber composites

摘要

Composites of recycled poly(ethylene terephthalate) (PET) reinforced with short glass fiber (GF) (0, 20, 30, and 40 wt %) were compounded in a single-screw extruder (SSE) and in a intermeshing corotating twin-screw extruder (TSE). An SSE fitted with a barrier double-flight screw melting section in between two single-flight sections and a TSE with a typical screw configuration for this purpose were used. The composites were subsequently injection molded at two different mold temperatures (10 and 120 degrees C), with all other operative molding parameters kept constant. The effects of processing conditions on composite microstructure, PET degree of crystallinity, and composite mechanical properties were evaluated. Appropriate dispersive and distributive mixing of the glass fiber throughout the PET matrix as well as fine composite mechanical and thermal-mechanical properties were achieved regardless of whether the composites were prepared in the SSE or TSE. The performance of the SSE was attributed to the efficiency of the barrier screw melting section in composite mixing. The mold temperature influenced the mechanical properties of the composites, by controlling of the degree of crystallinity of the PET in the composites. For a good balance of mechanical and thermal-mechanical properties, high mold temperatures are desirable, typically, 120 degrees C for a mold cooling time of 45 s. (C) 2008 Wiley Periodicals, Inc.