Preparation of rubber composites from ground tire rubber reinforced with waste-tire fiber through mechanical milling

摘要

Composites made from ground tire rubber (GTR) and waste fiber produced in tire reclamation were prepared by mechanical milling. The effects of the fiber content, pan milling, and fiber orientation on the mechanical properties of the composites were investigated. The results showed that the stress-induced mechanochemical devulcanization of waste rubber and the reinforcement of devulcanized waste rubber with waste-tire fibers could be achieved through comilling. For a comilled system, the tensile strength and elongation at break of revulcanized GTR/fiber composites reached maximum values of 9.6 MPa and 215.9%, respectively, with 5 wt % fiber. Compared with those of a composite prepared in a conventional mixing manner, the mechanical properties were greatly improved by comilling. Oxygen-containing groups on the surface of GTR particles, which were produced during pan milling, increased interfacial interactions between GTR and waste fibers. The fiber-filled composites showed anisotropy in the stress-strain properties because of preferential orientation of the short fibers along the roll-milling direction (longitudinal), and the adhesion between the fiber and rubber matrix was improved by the comilling of the fiber with waste rubber. The proposed process provides an economical and ecologically sound method for tire-rubber recycling. (c) 2006 Wiley Periodicals, Inc.