Agent distribution and water remaining of polyester nonwoven fabrics after-treated with polyurethane-citric acid

摘要

Polyester nonwoven fabric samples were used to treat with aqueous solutions of water-soluble polyurethane (PU) containing the foaming agent, citric acid, or the mixtures of foaming agent and citric acid to examine the water remaining and the degradation of PU under the simulative condition of under ground. The results reveal that the viscosity of PU solutions could affect the values of pickup and add-on. The water remaining values for PU containing citric acid are higher than those for PU containing the foaming agent and PU containing the foaming agent and citric acid. The pore structures, nonwoven construction, and the pores caused by the aggregation of PU within/on the treated nonwoven fabrics can affect the water remaining. From the observation of SEM and the comparison of FTIR, the degradation of water-soluble PU resin is proved, which could form the rough porous surface of PU resin on the fiber surface as a factor improving the water remaining. The value of water remaining for PU containing citric after 60 weeks' treatment is significantly higher than the pristine nonwoven fabric (control). (c) 2006 Wiley Periodicals, Inc.