Effect of filler treatments on rheological behavior of calcium carbonate and talc-filled polypropylene hybrid composites

摘要

Commercial stearic acid treated calcium carbonate (CaCO3) was used to make a comparative study on rheological behavior of the CaCO3 and talc-filled polypropylene (PP) hybrid composites with nontreated filler. Apparent shear viscosity and extrudate swell were investigated with variation of filler ratio and temperature with 30% by weight total of filler was used in PP composite. The Shimadzu capillary rheometer was used to evaluate shear viscosity and shear rate of the composite. It was found that the shear viscosities decrease with increasing shear rate. The apparent shear viscosity of the composite containing the stearic acid treated is slightly lower than untreated filler. Shear thickening behavior at higher shear rate has also shown by 15/15 treated composites at higher temperature about 220 degrees C and investigation by SEM has proved that filler being densely packed at that condition. Treated composites also exhibit lower swelling ratio value than untreated composite, and swelling ratio also decreases linearly with increasing temperature and the die length-diameter ratio. It is believed that dispersion of filler play an important role not only on shear viscosity but also on swelling ratio of PP composite. (c) 2006 Wiley Periodicals, Inc.