Curing characteristics and mechanical properties of alkali-treated grass-fiber-filled natural rubber composites and effects of bonding agent

摘要

To improve adhesion between fiber and matrix, natural rubber was reinforced with a special type of alkali-treated grass fiber (Cyperus Tegetum Rox b). The cure characteristics and mechanical properties of grass-fiber-filled natural rubber composites with different mesh sizes were studied with various fiber loadings. Increasing the amount of fibers resulted in the composites having reduced tensile strength but increased modulus. The better mechanical properties of the 400-mesh grass-fiber-filled natural rubber composite showed that the rubber/fiber interface was improved by the addition of resorcinol formaldehyde latex (RFL) as bonding agent for this particular formulation. The optimum cure time decreased with increases in fiber loading, but there was no appreciable change in scorch time. Although the optimum cure time of vulcanizates having RFL-treated fibers was higher than that of the other vulcanizates, it decreased with fiber loading in the presence of RFL as the bonding agent. But this value was lower than that of the rubber composite without RFL. Investigation of equilibrium swelling in a hydrocarbon solvent was also carried out. (c) 2006 Wiley Periodicals, Inc.