Rhodathiaborane reaction cycles driven by C2H4 and H-2: synthesis and characterization of [(H)(2)(PPh3)RhSB8H7(PPh3)] and [(eta(2)-C2H4)(PPh3)RhSB8H7(PPh3)]

摘要

New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by oxidation/reduction chemistry of the polyhedral boron-based clusters with ethelyne and dihydrogen.