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Design, optical and antimicrobial properties of extremely thin alumina films colored with silver nanospecies

机译:银纳米色超薄氧化铝膜的设计,光学和抗菌性能

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In this study, conditions for the fabrication of extremely thin and flexible anodic films decorated with silver nanowire arrays by alternating current treatments for the finishing of high purity and commercial aluminium foils were developed. For characterization of these porous films with a thickness of <= 1.0 mu m and encased silver species, inductively coupled plasma optical emission spectroscopy, X-ray diffraction and field emission scanning electron microscopy were used. Variable angle spectroscopic ellipsometry in the wavelength range of 200-1700 nm was also used to determine the influence of the deposited Ag content and the film thickness on the optical constants (n, k) of the fabricated alumina films. It is shown that due to surprisingly low k values of nano-Ag-in-alumina films in the visible and near IR regions these films could be applied as transparent films with an extremely low refractive index. In addition, the antimicrobial activity of the obtained films was assessed for the as-deposited and fully-encapsulated silver nanowire arrays against several widespread fungi and bacteria. The results obtained from in vitro tests indicated that the as-formed Ag-in-alumina films containing >= 19 mu g cm(-2) of silver possessed antimicrobial properties and could be promising as foodstuff packaging materials.
机译:在这项研究中,开发了通过交流电处理以完成高纯度铝箔和商用铝箔的极细且柔性阳极膜的工艺,这些阳极膜由银纳米线阵列装饰。为了表征厚度小于等于1.0μm的多孔膜并包封银,使用了电感耦合等离子体发射光谱,X射线衍射和场发射扫描电子显微镜。还使用波长在200-1700 nm范围内的变角光谱椭圆仪来确定沉积的Ag含量和膜厚对所制备氧化铝膜的光学常数(n,k)的影响。结果表明,由于在可见光区域和近红外区域中的纳米Ag-in-氧化铝薄膜的k值出人意料地低,这些薄膜可以用作具有极低折射率的透明薄膜。另外,评估了所获得的膜对沉积和完全包封的银纳米线阵列对几种广泛的真菌和细菌的抗微生物活性。从体外试验获得的结果表明,所形成的包含大于等于19μg cm(-2)的银的氧化铝中银膜具有抗菌性能,有望作为食品包装材料。

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