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A study on corrosion behaviors of Ni-Cr-Mo laser coating, 316 stainless steel and X70 steel in simulated solutions with H2S and CO2

机译:Ni-Cr-Mo激光涂层,316不锈钢和X70钢在H2S和CO2模拟溶液中的腐蚀行为研究

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摘要

Ni-Cr-Mo coating was prepared by a high power diode laser (HPDL) on X70 steel substrate (X70). In order to widen the application of this coating in oil industry, its surface morphology and corrosion behavior in simulated solutions separately with CO2, H2S as well as a mixed gas of them were studied and compared with those of X70 and 316 stainless steel (316 SS). The results show that X70 and 316 SS display inclusions on the surface before corrosion, while Ni-Cr-Mo coating exhibits a uniform and compact microstructure. Moreover, Ni-Cr-Mo coating has no change in morphology after corrosion, while X70 and 316 SS display severe corrosion and pitting corrosion, respectively. For each simulated solution, Ni-Cr-Mo coating exhibits higher corrosion resistance than X70 and 316 SS. Also, it shows higher polarization resistance than 316 SS and X70 as immersion time lasts, revealing an enhanced and stable anticorrosion performance. Furthermore, the variation trends of electrochemical response was opposite for X70 and 316 SS/Ni-Cr-Mo coating in simulated solutions with CO2, H2S as well as the mixed gas accordingly, which is caused by different corrosion mechanisms. (C) 2016 Elsevier B.V. All rights reserved.
机译:通过高功率二极管激光器(HPDL)在X70钢基底(X70)上制备Ni-Cr-Mo涂层。为了扩大该涂料在石油工业中的应用,研究了它在模拟溶液中分别与CO2,H2S以及它们的混合气体一起使用时的表面形态和腐蚀行为,并与X70和316不锈钢(316 SS)进行了比较。 )。结果表明,X70和316 SS在腐蚀之前在表面上显示出夹杂物,而Ni-Cr-Mo涂层则显示出均匀而致密的微观结构。此外,Ni-Cr-Mo涂层腐蚀后的形态没有变化,而X70和316 SS分别显示出严重的腐蚀和点蚀。对于每种模拟溶液,Ni-Cr-Mo涂层均具有比X70和316 SS更高的耐腐蚀性。而且,随着浸入时间的持续,它显示出比316 SS和X70更高的耐极化性,从而显示出增强且稳定的防腐蚀性能。此外,在模拟溶液中,CO2,H2S以及相应的混合气体下,X70和316 SS / Ni-Cr-Mo涂层的电化学响应变化趋势相反,这是由不同的腐蚀机理引起的。 (C)2016 Elsevier B.V.保留所有权利。

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