Binding Energy of Transition-Metal Complexes with Large -Conjugate Systems. Density Functional Theory vs Post-Hartree-Fock Methods

摘要

We systematically evaluated the binding energies of d10, d8, and d6 transition-metal complexes with various -conjugate systems such as Pt(PH_3)_2{C_2H_(4-n)(CH=CH_2)n}, Pd(PH_3)_2{C_2H_(4-n)(CH=CH_2)n}, [PtCl_3{C_2H_(4-n)-(CH=CH_2)n}]-, [PdCl_3{C_2H_(4-n)(CH=CH_2)n}]-, and [PtCl_5{C_2H_(4-n)(CH=CH_2)n}]- (n = 0-4) using the MP_2 to MP_4, CCSD(T), and density functional theory (DFT) methods. The MP4(SDQ) and CCSD(T) methods present a reliable binding energy, whereas the DFT method significantly underestimates the binding energy when the size of the -conjugate system is large. The underestimation occurs independently of the coordinate bonding nature; the -back-donation is stronger than the -donation in the Pt(0) complexes, as expected, they are comparable in the Pt(II) complexes, and only the -donation participates in the coordinate bond of the Pt(IV) complexes. The DFT method provides moderately stronger charge-transfer (CT) interaction than the MP4(SDQ) method, suggesting that the underestimation of the binding energy by the DFT method does not arise from the insufficient description of the CT interaction. From theoretical investigation of several model systems, it is concluded that the underestimation arises from the insufficient description of electron correlation effects.