On the role of frustration on the glass transition and polyamorphism of mesoscopically heterophase liquids

摘要

The model of heterophase fluctuations is developed accounting frustration of the mesoscopic solidlike fluctuons. Within the framework of this model, the glass transition and polyamorphous transformations are considered. It is shown that the frustration increases the temperature range in which the heterophase liquid state exists. the upper and lower boundaries of this temperature range are determined. These boundaries separate different phase states-amorphous solid, heterophase liquid, and fluid phases. Polyamorphous liquid-liquid transitions in the liquid are investigated. Frustration can call forth continuous fluid-solid phase transformation avoiding the first- or second-order phase transition. Conditions under which the first-order phase transition fraction takes place are formulated. Two scenarios of the first-order liquid-liquid polyamorphous transformation are described. As an example the glacial phase formation and the first-order liquid-liquid phase transition in triphenyl phosphate are considered and discussed. Impact of frustration on the liquid crystallization and crystallinity of the glassy state is studied.