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Infrared intensity in small ammonia and water clusters

机译:小型氨水簇中的红外强度

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Helium droplet technique has been used in order to measure the strength of the infrared absorption in small ammonia and water clusters as a function of size.Hydrogen bonding in ammonia and water dimers causes an enhancement of the intensity of the hydrogen stretching bands by a factor of four and three,respectively.Two types of the hydrogen bonded clusters show different size dependence of the infrared intensity per hydrogen bond.In ammonia (NH_3)_2 and (NH_3)_3 it is close to the crystal value.In water clusters,it increases monotonically with cluster size being in tetramers,a factor of two smaller than in the ice.The measured infrared intensity in water clusters is found to be a factor of two to three smaller as compared to the results of numerical calculations.
机译:氦滴技术已被用于测量小型氨和水团簇中红外吸收的强度与尺寸的关系。氨和水二聚体中的氢键使氢拉伸带的强度提高了两种类型的氢键团簇对每个氢键的红外强度的大小依赖性不同。在氨(NH_3)_2和(NH_3)_3中,它接近晶体值。在水簇中,它增加团簇大小在四聚体中单调,比冰中小2倍。与数值计算结果相比,水团簇中测得的红外强度小2到3倍。

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